|
| Product Name: | RuPhos Pd G3 | | Synonyms: | Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [RuPhos Palladacycle];Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98%;RuPhos Pd G3 95%;Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);(2-Dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate;RuPhos Pd G3;RuPhos-G3-Palladacycle;RuPhos-Pd-G3 | | CAS: | 1445085-77-7 | | MF: | C43H57NO5PPdS- | | MW: | 837.375141 | | EINECS: | | | Product Categories: | Buchwald Ligands&Precatalysts;Buchwald Precatalysts Series;Pd | | Mol File: | 1445085-77-7.mol |  |
| | RuPhos Pd G3 Chemical Properties |
| Melting point | 188-196°C (decomposition) | | storage temp. | under inert gas (nitrogen or Argon) at 2–8 °C | | form | Powder | | color | white | | CAS DataBase Reference | 1445085-77-7 |
| | RuPhos Pd G3 Usage And Synthesis |
| Reaction |
- Palladium catalyst used for facile, C-N cross-coupling reactions.
- A practical synthesis of indoles via a Pd-catalyzed C-N ring formation.
| | Uses | RuPhos Pd G3 can be used as a pre-catalyst in the following protocols:
- Palladium-catalyzed Suzuki coupling of 5-p-toluenesulfonyltetrazoles with arylboronic acids to synthesize 1,5-disubstituted tetrazoles.
- Suzuki-Miyaura catalyst-transfer polycondensation (SCTP) of 3-alkylthiophenes in the presence of N-methylimidodiacetic (MIDA)-boronate monomers.
- Suzuki-Miyaura-cross-coupling of aminothiophenes.
| | General Description | RuPhos Pd G3 is a third generation (G3) Buchwald precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. It is air-, moisture-, and thermally-stable and is highly soluble in a wide range of common organic solvents. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio. |
| | RuPhos Pd G3 Preparation Products And Raw materials |
|
