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| | TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Basic information | | Reaction |
| | TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Chemical Properties |
| Melting point | 160 °C (dec.) (lit.) | | storage temp. | Inert atmosphere,Store in freezer, under -20°C | | form | solid | | color | white to light blue | | Sensitive | air sensitive, moisture sensitive |
| | TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Usage And Synthesis |
| Reaction |
- Useful catalyst for the Ullmann synthesis.
- Catalytic asymmetric [2,3]-Sigmatropic rearrangement of sulfur ylides.
- Precatalyst for enantioselective N–H insertion reactions with diazoesters and anilines.
| | Uses | Tetrakis(acetonitrile)copper(I) hexafluorophosphate can be employed as a catalyst for the synthesis of triazolo[1,2-a]indazole-1,3,8-trione and 2H-indazolo[2,1-b]phthalazine-trione derivatives by the reaction of aryl aldehydes, dimedone and urazole or phthalhydrazide, respectively.
It can also be used as a copper precursor:
- For the formation of Cu2S/CdS nanorod junctions by cationic exchange process.
- To synthesize monometallic copper macrocyclic biquinazoline ligand [Cu(Mabiq)].
- To prepare the cuprous complex [Cu(2-iQBO)(POP)]PF6]; where 2-iQBO=2-(1′-isoquinolyl)benzoxazole and POP=bis[2-(diphenylphosphino)phenyl]ether, which can form luminescent pseudo-polymorphs.
- For the synthesis of [Cu(NHC)2]PF6 complexes [(NHC = N-heterocyclic carbene] which can be further used in the hydrosilylation of carbonyl compounds.
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| | TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Preparation Products And Raw materials |
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