ChemicalBook Product Catalog Organic Chemistry Phosphines BENZYLDI-1-ADAMANTYLPHOSPHINE

BENZYLDI-1-ADAMANTYLPHOSPHINE

BENZYLDI-1-ADAMANTYLPHOSPHINE Basic information
Reaction
Product Name:BENZYLDI-1-ADAMANTYLPHOSPHINE
Synonyms:Di(1-adamantyl)benzylphosphine 95%;Benzyldi-1-adaMantylphosphine,85%;Di(adaMantan-1-yl)(benzyl)phosphine;Phosphine,(phenylMethyl)bis(tricyclo[3.3.1.13,7]dec-1-yl)-;Di(1-adamantyl)benzylphosphine;BENZYLDI-1-ADAMANTYLPHOSPHINE;CATACXIUM ABN;Benzyldi-1-adamantylphosphine,min.85%[cataCXiumABn]
CAS:395116-70-8
MF:C27H37P
MW:392.56
EINECS:1312995-182-4
Product Categories:Achiral Phosphine;Aryl Phosphine;organophosphine ligand
Mol File:395116-70-8.mol
BENZYLDI-1-ADAMANTYLPHOSPHINE Structure
BENZYLDI-1-ADAMANTYLPHOSPHINE Chemical Properties
Melting point 183°C
storage temp. Inert atmosphere,Store in freezer, under -20°C
form Powder
color yellow
Sensitive air sensitive
BRN 9359745
Safety Information
Safety Statements 24/25
WGK Germany 3
HS Code 29319090
MSDS Information
BENZYLDI-1-ADAMANTYLPHOSPHINE Usage And Synthesis
ReactionUseful ligand for Sonogashira coupling reaction. Reactions of 395116-70-8
Chemical PropertiesWhite to light yellow solid
UsesCatalyst for:
  • Sonogashira coupling reaction
  • Ruthenium-catalyzed amination of secondary alcohols. with ammonia
  • Rhodium-catalyzed regioselective hydroformylation of alkenes
  • Reductive carbonylation
  • Suzuki coupling reaction
Usessuzuki reaction
General Descriptionsold in collaboration with Solvias AG
BENZYLDI-1-ADAMANTYLPHOSPHINE Preparation Products And Raw materials
Raw materialsDI-1-ADAMANTYLPHOSPHINE-->Benzyl bromide-->DI-1-ADAMANTYLPHOSPHINE OXIDE-->BENZYL IODIDE
Butyldi-1-adamantylphosphine Di(1-adaMantyl)chlorophosphine Diphenyl-2-pyridylphosphine Di(1-adamantyl)-n-butylphosphine hydriodide DI-1-ADAMANTYLPHOSPHINE DI-I-PROPYLPHOSPHINE BENZYLDI-1-ADAMANTYLPHOSPHINE
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