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(S)-(+)-2-Phenylglycinol

(S)-(+)-2-Phenylglycinol Basic information
Product Name:(S)-(+)-2-Phenylglycinol
Synonyms:L-(+)-ALPHA-PHENYLGLYCINOL;L-(+)-A-PHENYLGLYCINOL;L-beta-Aminophenethyl alcohol;H-PHG-OL;H-PHENYLGLYCINOL;H-L-PHG-OL;D-2-PHENYLGLYCINOL;BENZENEETHANOL, B-AMINO-, (BS)-
CAS:20989-17-7
MF:C8H11NO
MW:137.18
EINECS:606-683-7
Product Categories:Amines;Aromatics;Chiral Reagents;Intermediates & Fine Chemicals;Pharmaceuticals;Amino Alcohols (Chiral);Asymmetric Synthesis;Chiral Building Blocks;Synthetic Organic Chemistry;Amino alcohols;Amino Acids & Derivatives;Amino Acids 13C, 2H, 15N;chiral;Chiral Reagent;Phenylglycine [Phg];Alcohols and Derivatives;Pharmaceutical Intermediates
Mol File:20989-17-7.mol
(S)-(+)-2-Phenylglycinol Structure
(S)-(+)-2-Phenylglycinol Chemical Properties
Melting point 76-79 °C
alpha -25.5 º (c=6, MeOH)
Boiling point 252.03°C (rough estimate)
density 1.0630 (rough estimate)
refractive index 30 ° (C=1, EtOH)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
form Crystalline Powder
pka12.51±0.10(Predicted)
color White to pale yellow
optical activity[α]19/D +33°, c = 0.75 in 1 M HCl
Water Solubility Soluble in chloroform, dimethylsulfoxide and methanol. Limited solubility in water.
Sensitive Air Sensitive
BRN 3196190
CAS DataBase Reference20989-17-7(CAS DataBase Reference)
Safety Information
Hazard Codes C,T
Risk Statements 34-36/37/38-23/24/25
Safety Statements 22-24/25-45-36/37/39-26-37
WGK Germany 3
F 2-10
HS Code 29052900
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
(S)-(+)-2-Phenylglycinol Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
Uses(S)-(+)-2-Phenylglycinol is used in the synthesis of chiral, unsymmetrical bisoxazolines. It is used as a reagent for the resolution of acids via the easily hydrolyzed amides.
Uses(S)-(+)-2-Phenylglycinol is a chiral arylalkylamine used as organocatalysts. Used in the synthesis and chiral recognition properties of novel fluorescent chemosensors for amino acid.
(S)-(+)-2-Phenylglycinol Preparation Products And Raw materials
Preparation Products(S)-(+)-4-Phenyl-2-oxazolidinone-->(S)-4-PHENYL-1,3-OXAZOLIDINE-2-THIONE-->2-Benzylamino-2-methyl-1-propanol-->(S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE)-->(S)-4-PHENYL-1,3-THIAZOLIDINE-2-THIONE-->(-)-Benzotetramisole-->(5S)-3,4,5,6-TETRAHYDRO-5-PHENYL-N-(BENZYLOXYCARBONYL)-4(H)-1,4-OXAZIN-2-ONE-->FMOC-L-PHENYLGLYCINOL
Boc-N-Methyl-L-phenylglycine (S)-(+)-4-PHENYL-2-OXAZOLIDINONE Cbz-D-Alpha-Phenylglycinol,Cbz-D-Alpha-Phenylglycinol (S)-(+)-N-(3,5-DINITROBENZOYL)-ALPHA-PHENYLGLYCINE N-BOC-D/L-PHENYLGLYCINOL (-)-BICUCULLINE METHCHLORIDE, 1(S),9(R) Ketorolac tromethamine (-)-BICUCULLINE METHOBROMIDE Boc-DL-Alpha-Phenylglycinol,Boc-DL-Alpha-Phenylglycinol N-ME-PHG-OH (+)-Bicuculline Amlodipine Besylate ALTRENOGEST A,A-DIPHENYL-4-MORPHOLINEACETIC ACID, SODIUM SALT BOC-DL-phenylglycinol,BOC-DL-phenylglycinol AMINO ACIDS Cbz-L-Alpha-Phenylglycinol,Cbz-L-Alpha-Phenylglycinol Fmoc-L-Alpha-Phenylglycinol,Fmoc-L-Alpha-Phenylglycinol
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