ChemicalBook Product Catalog Organic Chemistry Amides Naphthenic amines derivatives 2,4-Dibromoaniline

2,4-Dibromoaniline

2,4-Dibromoaniline Basic information
Product Name:2,4-Dibromoaniline
Synonyms:2,4-DIBROMOANILINE;2,4-DIBROMOBENZENAMINE;2 4-DIBROMOANILINE 98% (GC);2,4-Dibromoaniline, 98+%;2,4-Dibromanilin;2,4-dibromo-benzenamin;2,4-Dibromoaniline 98%;2,4-Dibromoaniline >
CAS:615-57-6
MF:C6H5Br2N
MW:250.92
EINECS:210-434-4
Product Categories:Building Blocks;C6;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks;Anilines, Amides & Amines;Bromine Compounds;Amines;C2 to C6;Nitrogen Compounds
Mol File:615-57-6.mol
2,4-Dibromoaniline Structure
2,4-Dibromoaniline Chemical Properties
Melting point 78-80 °C (lit.)
Boiling point 156 °C (24 mmHg)
density 2.26
refractive index 1.5800 (estimate)
Fp 156°C/24mm
storage temp. Store below +30°C.
Water Solubility Insoluble in water
form powder to crystal
pka1.83±0.10(Predicted)
color White to Light yellow
BRN 2206653
CAS DataBase Reference615-57-6(CAS DataBase Reference)
NIST Chemistry ReferenceBenzenamine, 2,4-dibromo-(615-57-6)
EPA Substance Registry System2,4-Dibromoaniline (615-57-6)
Safety Information
Hazard Codes Xn,Xi,N,T
Risk Statements 36/37/38-33-20/21/22-51/53-25
Safety Statements 36/37/39-26-61-45
RIDADR 2811
WGK Germany 3
TSCA T
HazardClass 6.1
PackingGroup III
HS Code 29214210
MSDS Information
ProviderLanguage
2,4-Dibromoaniline English
ACROS English
ALFA English
2,4-Dibromoaniline Usage And Synthesis
Chemical Propertiesbeige powder
Uses2,4-Dibromoaniline can be used as:
  • A starting material to synthesize acetylenic amine by reacting with trimethylsilylacetylene, which is used as a ligand to prepare the bis-amido complex of Ti(IV).
  • A substrate in the Pd-catalyzed ortho-selective cross-coupling reactions of dihaloarenes with Grignard reagents.
  • A reactant to prepare dialkyl-substituted aminoaryl sulfides using a Grignard reagent.
  • A starting material to synthesize substituted 2-mercapto benzimidazoles.

Uses2,4-Dibromoaniline is used in preparation of glycopeptides and targeted bifunctional degraders.
Purification MethodsCrystallise the aniline from aqueous EtOH. The picrate has m 124o. [Beilstein 12 H 655, 12 I 326, 12 II 356, 12 III 1471, 12 IV 1532.]
2,4-Dibromoaniline Preparation Products And Raw materials
Preparation ProductsAcetamide, 2-chloro-N-(2,4-dibromophenyl)--->6-Bromo-2-(methylthio)benzo[d]thiazole-->N-(2,4-dibromophenyl)-4-fluorobenzamide-->ethyl 5-bromo-2-methyl-1H-indole-3-carboxylate-->2,4-DIBROMOBIPHENYL-->2,4-DIBROMOPHENYL ISOCYANATE
AKOS B029749 3,5-Dibromoaniline hydrochloride,3,5-Dibromoaniline, HCl 2-Methyl-4,6-dibromoaniline 1,2-DIBROMOETHYLENE 2,4,6-TRIBROMOPHENYL ISOCYANATE 2,4-DIBROMOPENTANE 2-[(benzenesulfonyl)methyl]-3,6-dibromoaniline 3-AMINO-2,4,6-TRIBROMOBENZOIC ACID Α,Β-DIBROMOPROPIONIC ACID 1,5-diamino-2,4,6,8-tetrabromoanthraquinone N-ACETYL-2,4-DIBROMOANILINE 2,2-Bis(bromomethyl)propane-1,3-diol 2-AMINO-3,5-DIBROMO-6-FLUOROBENZOIC ACID 2,5-Dichloro-4,6-dibromoaniline 3,4-DIBROMOANILINE 4,4'-oxybis[2,6-dibromoaniline] 2,4,6-TRIBROMOPHENYL ISOTHIOCYANATE 1,3-Bis(bromomethyl)benzene
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