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2-BIPHENYLBORONIC ACID

2-BIPHENYLBORONIC ACID Basic information
Product Name:2-BIPHENYLBORONIC ACID
Synonyms:2-Boronobiphenyl, 2-Phenylbenzeneboronic acid;2-Biphenylboronic Acid (contains varying aMounts of Anhydride);2-Biphenylboronic Acid ;TIMTEC-BB SBB005895;Boronic acid, B-[1,1'-biphenyl]-2-yl-;2-Biphenylboronic acid (2-Phenylphenyl)boranediol;2-Biphenylboronic acid, >=98%;BIPHENYL-2-BORONIC ACID
CAS:4688-76-0
MF:C12H11BO2
MW:198.03
EINECS:670-315-1
Product Categories:Boronic Acids & Esters;Boronic acid;Boronic Acids & Esters;Ring Systems;Aryl;Boronic Acids;Boronic Acids and Derivatives;blocks;BoronicAcids
Mol File:4688-76-0.mol
2-BIPHENYLBORONIC ACID Structure
2-BIPHENYLBORONIC ACID Chemical Properties
Melting point 167-172 °C (lit.)
Boiling point 404.0±38.0 °C(Predicted)
density 1.18
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility DMSO (Slightly), Methanol (Slightly, Sonicated)
pka8.50±0.58(Predicted)
form Powder or Low Melting Solid
color White to yellow
Water Solubility Insoluble in water.
λmax250nm(CH2Cl2)(lit.)
BRN 3031806
InChIKeyHYCYKHYFIWHGEX-UHFFFAOYSA-N
CAS DataBase Reference4688-76-0(CAS DataBase Reference)
Safety Information
Hazard Codes C,Xi,Xn
Risk Statements 36/37/38-20/21/22
Safety Statements 26-36-60-37
WGK Germany 3
Hazard Note Corrosive
HazardClass IRRITANT
HS Code 29310095
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
2-BIPHENYLBORONIC ACID Usage And Synthesis
Chemical PropertiesOff-white powder
UsesReactant involved in:
  • Suzuki-Miyaura cross-coupling reactions with arylhalides, dibromovinyl precursors, alkenyl tosylates and mesylates, and quinoline carboxylates
  • Intramolecular Friedel-Crafts alkylation for synthesis of chiral tetralins
  • Hydroxylation to phenols
  • Oxidative coupling iwth alkynes
Usessuzuki reaction
2-BIPHENYLBORONIC ACID Preparation Products And Raw materials
Preparation Products(9-(4-IODOPHENYL))-9H-CARBAZOLE-->o-Terphenyl-->1,3,5-Triazine, 2,4,6-tris([1,1':2',1''-terphenyl]-3-yl)--->2,4-DINITRO-6-PHENYLPHENOL
4'-ETHYL-4-BIPHENYLBORONIC ACID 3-FLUORO-4-BIPHENYLBORONIC ACID 4'-CHLORO-4-BIPHENYLBORONIC ACID 4-BIPHENYLBORONIC ACID, PINACOL ESTER 1-BIPHENYLENYLBORONIC ACID 4'-FLUORO-4-BIPHENYLBORONIC ACID 4'-METHOXY-4-BIPHENYLBORONIC ACID 4'-METHYL-4-BIPHENYLBORONIC ACID 4'-BENZOYL-4-BIPHENYLBORONIC ACID Phenylboronic acid 4'-BROMO-4-BIPHENYLBORONIC ACID 2-P-TERPHENYLBORONIC ACID 4,4'-Biphenylboronic acid 2-Fluoro-4-biphenylboronic acid, pinacol ester,3-Fluoro-4-biphenylboronic acid, pinacol ester RARECHEM AH PB 0064 3',4'-DICHLORO-4-BIPHENYLBORONIC ACID 4'-(TRIFLUOROMETHYL)-4-BIPHENYLBORONIC ACID 3-FLUORO-4-BIPHENYLBORONIC ACID
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