ChemicalBook Product Catalog Organic Chemistry Organometallic compounds Organomagnesium 3,5-DIMETHYLPHENYLMAGNESIUM BROMIDE

3,5-DIMETHYLPHENYLMAGNESIUM BROMIDE

3,5-DIMETHYLPHENYLMAGNESIUM BROMIDE Basic information
Product Name:3,5-DIMETHYLPHENYLMAGNESIUM BROMIDE
Synonyms:3,5-DIMETHYLPHENYLMAGNESIUM BROMIDE;3,5-dimethylphenylmagnesium bromide solution;3,5-DIMETHYLPHENYLMAGNESIUM BROMIDE, 0.5M SOLUTION IN TETRAHYDROFURAN;3,5-Dimethylphenylmagnesium Bromide 1.0 M In Diethyl Ether;3,5-Xylylmagnesium bromide;3,5-Dimethylphenylmagnesium bromide solution 0.5 in THF;3,5-Dimethylphenylmagnesium bromide, 0.5M solution in THF, AcroSeal;3,5-DiMethylphenylMagnesiuM broMide, 0.5 M solution in THF, SpcSeal
CAS:34696-73-6
MF:C8H9BrMg
MW:209.37
EINECS:
Product Categories:Grignard Reagent;Aryl;Grignard Reagents;Organometallic Reagents;Chemical Synthesis;Grignard Reagents;Organometallic Reagents
Mol File:34696-73-6.mol
3,5-DIMETHYLPHENYLMAGNESIUM BROMIDE Structure
3,5-DIMETHYLPHENYLMAGNESIUM BROMIDE Chemical Properties
Boiling point 65 °C
density 0.950 g/mL at 25 °C
Fp 1 °F
storage temp. 2-8°C
form Liquid
color Yellow to brown
Water Solubility It reacts with water.
Sensitive Air & Moisture Sensitive
Safety Information
Hazard Codes F,C,Xn
Risk Statements 11-14-19-22-34-40-36/37
Safety Statements 16-26-33-36/37/39-45-36/37
RIDADR UN 2924 3/PG 2
WGK Germany 1
HazardClass 3
HS Code 29310099
MSDS Information
ProviderLanguage
SigmaAldrich English
3,5-DIMETHYLPHENYLMAGNESIUM BROMIDE Usage And Synthesis
Uses3,5-Dimethylphenylmagnesium bromide is used as pharmaceutical intermediate.
Uses3,5-Dimethylphenylmagnesium bromide solution can be used:
  • As a starting material for the synthesis of diarylborinic acids, which on Suzuki coupling with vinyl triflate yield penultimate methyl ester.
  • To prepare 3,5-dimethyl-p-terphenyl by reacting with biphenylsulfonate in the presence of dppfNiCl2 catalyst.

3,5-DIMETHYLPHENYLMAGNESIUM BROMIDE Preparation Products And Raw materials
Preparation Products6-(3,5-DIMETHYLPHENYL)-6-OXOHEXANOIC ACID
2,5-DIMETHOXYPHENYLMAGNESIUM BROMIDE 5-Chloro-2-MethoxyphenylMagnesiuM broMide, 0.50M in 2-MeTHF Methylmagnesium Bromide 2,3-DIMETHYLPHENYLMAGNESIUM BROMIDE, 0.5M SOLUTION IN TETRAHYDROFURAN,2,3-DIMETHYLPHENYLMAGNESIUM BROMIDE Zinc chloride 2,4-DIMETHOXYPHENYLMAGNESIUM BROMIDE M-TOLYLMAGNESIUM CHLORIDE (3,5 BIS(TRIFLUOROMETHYL)PHENYL)MAGNESIUM BROMIDE 2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE,2,6-Dimethylphenylmagnesium bromide solution,2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE, 1.0 M SOLUTION IN TETRAHYDROFURAN 4-TERT-BUTYL-2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE 2,5-DIMETHYLPHENYLMAGNESIUM BROMIDE,2,5-DIMETHYLPHENYLMAGNESIUM BROMIDE, 0.5M SOLUTION IN TETRAHYDROFURAN 2,4-DIMETHYLPHENYLMAGNESIUM BROMIDE,2,4-dimethylphenylmagnesium bromide solution,2,4-DIMETHYLPHENYLMAGNESIUM BROMIDE, 0.5M SOLUTION IN TETRAHYDROFURAN 3,4-DIMETHYLPHENYLMAGNESIUM BROMIDE 3,5-DIMETHYLPHENYLMAGNESIUM BROMIDE 2 4-DIMETHYLPHENYLMAGNESIUM BROMIDE 0.& 3,5-dimethyl-4-methoxyphenylmagnesium bromide 2,3,5,6-TETRAMETHYLPHENYLMAGNESIUM BROMIDE 2,3,4,5,6-PENTAMETHYLPHENYLMAGNESIUM BROMIDE
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