ChemicalBook Product Catalog Organic Chemistry Amides Acyclic polyamines and their derivatives 2-METHYL-N-(PHENYLMETHYLENE)-2-PROPYLAMINE

2-METHYL-N-(PHENYLMETHYLENE)-2-PROPYLAMINE

2-METHYL-N-(PHENYLMETHYLENE)-2-PROPYLAMINE Basic information
Product Name:2-METHYL-N-(PHENYLMETHYLENE)-2-PROPYLAMINE
Synonyms:N-tert-Butylbenzylimine;N-tert-Butylbenzylimine 97%;N-Benzylidene-1,1-dimethylethanamine;N-Benzylidene-2-methyl-2-propanamine;N-Benzylidene-2-methylpropane-2-amine;N-Benzylidene-N-tert-b;N-tert-butyl-1-phenylmethanimine;N-tert-butyl-1-phenyl-methanimine
CAS:6852-58-0
MF:C11H15N
MW:161.24
EINECS:
Product Categories:Organic Building Blocks;Building Blocks;Imines/Amidines;Nitrogen Compounds;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks
Mol File:6852-58-0.mol
2-METHYL-N-(PHENYLMETHYLENE)-2-PROPYLAMINE Structure
2-METHYL-N-(PHENYLMETHYLENE)-2-PROPYLAMINE Chemical Properties
Melting point -30
Boiling point 209 °C(lit.)
density 0.906 g/mL at 25 °C(lit.)
refractive index n20/D 1.52(lit.)
Fp 173 °F
form liquid
pka6.31±0.50(Predicted)
color Colourless to light yellow
Specific Gravity0.906
EPA Substance Registry System2-Propanamine, 2-methyl-N-(phenylmethylene)- (6852-58-0)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 22-36/37/38-40-42/43
Safety Statements 26-36
WGK Germany 3
Hazard Note Irritant
HS Code 29215900
MSDS Information
ProviderLanguage
SigmaAldrich English
2-METHYL-N-(PHENYLMETHYLENE)-2-PROPYLAMINE Usage And Synthesis
Chemical PropertiesColorless to yellow liquid
Synthesis Reference(s)The Journal of Organic Chemistry, 53, p. 5856, 1988 DOI: 10.1021/jo00260a012
General DescriptionIn vitro metabolism of N-benzyl-tert-butylamine in male hamster hepatic microsomal preparations has been studied. Kinetic studies of frustrated Lewis pair (FLP)-catalyzed hydrogenation and deuteration of N-benzylidene-tert-butylamine suggests that the reaction proceeds via autoinductive catalysis.
2-METHYL-N-(PHENYLMETHYLENE)-2-PROPYLAMINE Preparation Products And Raw materials
Preparation ProductsN-TERT-BUTYLBENZAMIDE-->2-BORONOBENZALDEHYDE, PINACOL ESTER-->N-(tert-Butyl)benzylamine-->N-tert-ButylbenzylaMine Hydrochloride
P-NITROBENZYLIDENE TERT-BUTYLAMINE 2,4-DICHLORO-6-([(1,1-DIETHYLPROP-2-YNYL)IMINO]METHYL)PHENOL 2-(3,4-DIMETHOXYPHENYL)-4,4-DIMETHYL-4,5-DIHYDRO-1,3-OXAZOLE N-TERT-BUTYL-ALPHA-(2-SULFOPHENYL)NITRO& N-TERT-BUTYL-ALPHA-(2,4,6-TRIMETHOXY-PHENYL)NITRONE, 99 5,6-DIHYDRO-2-PHENYL-4,4,6-TRIMETHYL-1,3(4H)-OXAZINE 2-(2-METHOXYPHENYL)-4,4-DIMETHYL-2-OXAZOLINE 2-(2,6-DIMETHOXYPHENYL)-4,4-DIMETHYL-2-OXAZOLINE BENZYLIDENE(2-HYDROXYIMINO-1,1-DIMETHYLETHYL)AMMONIUMOLATE PTIO 2-(4-METHOXYPHENYL)-4,4-DIMETHYL-4,5-DIHYDRO-1,3-OXAZOLE 4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE 2-[(3,5-DICHLORO-2-HYDROXYBENZYLIDENE)AMINO]-2-METHYLPROPANE-1,3-DIOL 2-[1-(3,5-DIMETHYLPHENYL)-2-NAPHTHYL]-4,5-DIHYDRO-4,4-DIMETHYLOXAZOLE CARBOXY-PTIO N-TERT-BUTYL-ALPHA-PHENYLNITRONE 2-(4-Carboxyphenyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide 2-(4-NITROPHENYL)-4,4,5,5-TETRAMETHYLIMIDAZOLINE-3-OXIDE-1-OXYL
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