ChemicalBook Product Catalog Pharmaceutical intermediates Heterocyclic compound Pyridine compound Methylpyridine 2-Bromo-6-methylpyridine

2-Bromo-6-methylpyridine

2-Bromo-6-methylpyridine Basic information
Product Name:2-Bromo-6-methylpyridine
Synonyms:2-BROMO-6-PICOLINE;6-BROMO-2-PICOLINE;2-BroMo-6-Methylpyridine, 97+%;2 - broMine - 6 - Methyl pyridine;Pyridine, 2-bromo-6-methyl-;2-BROMO-6-METHYLPYRIDINE;Bromomethylpyridine,ca.97%;2-Bromo-6-methylpyrdine
CAS:5315-25-3
MF:C6H6BrN
MW:172.02
EINECS:226-173-4
Product Categories:Bromopyridines;Halopyridines;Boronic Acid;C6Heterocyclic Building Blocks;Halogenated Heterocycles;Heterocyclic Building Blocks;blocks;Bromides;Pyridines;Pyridine;pyridine derivative;Halides;Heterocycles;Pyridines, Pyrimidines, Purines and Pteredines;compounds of pyridine;bc0001
Mol File:5315-25-3.mol
2-Bromo-6-methylpyridine Structure
2-Bromo-6-methylpyridine Chemical Properties
Boiling point 102-103 °C/20 mmHg (lit.)
density 1.512 g/mL at 25 °C (lit.)
refractive index n20/D 1.562(lit.)
Fp 207 °F
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform, Ethyl Aceate
form Liquid
pka1.51±0.10(Predicted)
Specific Gravity1.512
color Clear colorless to yellow
Water Solubility Soluble in chloroform, ethyl aceate. Not miscible or difficult to mix with water.
BRN 107322
InChIKeySOHDPICLICFSOP-UHFFFAOYSA-N
CAS DataBase Reference5315-25-3(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HazardClass IRRITANT
HS Code 29333990
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
2-Bromo-6-methylpyridine Usage And Synthesis
Chemical PropertiesLight yellow liquid
Uses2-Bromo-6-methylpyridine is a halogenated pyridine derivative used is a building block in the preparation of nitrogen containing heterocyclic compounds.
Uses2-Bromo-6-methylpyridine may be used in the synthesis of the following:
  • 6,6′-dimethyl-2,2′-bipyridine
  • 6-methyl-2-pyridyl-2-pyridylmethanone
  • 2-methyl-6-(trimethylsilyl)-pyridine
  • N,N′-bis-(6-methylpyrid-2-yl)-(1R,2R)-1,2- diaminocyclohexane (cydiampy)
  • 2-methyl-6-(trimethylstannanyl)pyridine
  • 2-(6-methylpyridin-2-yl)propan-2-ol
  • bis[(2-bromo-6-methylpyridinium)hexafluorosilicate] monohydrate
Synthesis Reference(s)Journal of the American Chemical Society, 76, p. 3168, 1954 DOI: 10.1021/ja01641a017
General Description2-Bromo-6-methylpyridine is a bromopyridine derivative. It is formed when 2-chloro-6-methylpyridine is heated with bromotrimethylsilane. Its synthesis from various methods have been reported.
2-Bromo-6-methylpyridine Preparation Products And Raw materials
Preparation Products6-Bromopyridine-2-carbaldehyde-->6-Methoxypyridine-2-carbaldehyde-->6-IODO-PYRIDINE-2-CARBOXYLIC ACID METHYL ESTER-->6,6'-Dimethyl-2,2'-dipyridyl-->6-Bromo-4-nitropyridine-2-carboxylic acid ,98%-->5,5'-DIMETHYL-2,2'-DIPYRIDYL-->6-Methyl-2-pyridinecarboxylic acid-->Pyridine, 2-Methyl-6-(1H-pyrazol-3-yl)--->2-METHYL-6-VINYLPYRIDINE-->2-bromo-6-methylpyridin-4-amine-->6-Trifluoromethyl-pyridine-2-carbaldehyde-->2-Propyn-1-ol, 3-(6-methyl-2-pyridinyl)- (9CI)-->2-(CHLOROMETHYL)-6-PHENYLPYRIDINE-->6-Methyl-2,3'-bipyridine
2-Bromo-6-(trifluoromethyl)pyridine 6-BROMO-2,2'-BIPYRIDINE 1-Hexadecylpyridinium bromide 2-BROMOMETHYL-PYRIDINE 2-Bromo-6-phenylpyridine 6,6'-DIBROMO-2,2'-DIPYRIDYL 2-Bromopyridine 6-Bromo-2-pyridinecarbonitrile 4-Methylpyridine 6-Bromopicolinic acid 2-BROMO-3-FLUORO-6-PICOLINE 2-Acetyl-6-bromopyridine Azamethiphos 2-Bromo-6-methylpyridine 2,6-Lutidine 2-BROMO-4,6-DIMETHYLPYRIDINE 2-BROMO-4,6-DIMETHYLNICOTINONITRILE 2,5,6-Tribromo-3-methylpyridine
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