ChemicalBook Product Catalog Chemical Reagents Organic reagents Esters Methyl ester compound Methyl 2-iodobenzoate

Methyl 2-iodobenzoate

Methyl 2-iodobenzoate Basic information
Product Name:Methyl 2-iodobenzoate
Synonyms:2-IODOBENZOIC ACID METHYL ESTER;METHYL O-IODOBENZOATE;METHYL 2-IODOBENZOATE;BENZOIC ACID, 2-IODO-, METHYL ESTER;IBM;O-IODOBENZOIC ACID METHYL ESTER;RARECHEM AL BF 0562;2-iodo-benzoicacimethylester
CAS:610-97-9
MF:C8H7IO2
MW:262.04
EINECS:210-243-6
Product Categories:Iodine Compounds;C8 to C9;Aromatic Esters;Acids & Esters;Carbonyl Compounds;Esters;bc0001;610-97-9
Mol File:610-97-9.mol
Methyl 2-iodobenzoate Structure
Methyl 2-iodobenzoate Chemical Properties
Melting point 64°C
Boiling point 149-150 °C/10 mmHg (lit.)
density 1.784 g/mL at 25 °C (lit.)
refractive index n20/D 1.604(lit.)
Fp >230 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Chloroform, Ethyl Acetate (Slightly), Methanol
form Crystalling or Flaky Powder
color White
Water Solubility INSOLUBLE
Sensitive Light Sensitive
BRN 2206859
Stability:Light Sensitive
InChIKeyBXXLTVBTDZXPTN-UHFFFAOYSA-N
CAS DataBase Reference610-97-9(CAS DataBase Reference)
NIST Chemistry ReferenceMethyl-2-iodobenzoate(610-97-9)
EPA Substance Registry SystemBenzoic acid, 2-iodo-, methyl ester (610-97-9)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-24/25
WGK Germany 3
TSCA T
HazardClass IRRITANT
HS Code 29163990
MSDS Information
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Methyl 2-iodobenzoate English
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Methyl 2-iodobenzoate Usage And Synthesis
Chemical PropertiesCLEAR YELLOW LIQUID
UsesMethyl 2-iodobenzoate may be used in the preparation of:
  • N-substituted 4-methylene-3,4-dihydro-1(2H)-isoquinolin-1-ones
  • methyl diphenylacetylene-2-carboxylate
  • methyl 2-heptynylphenylbenzoate
  • (E)-2-[3-[3-[2-(7-chloro-2-quinolinyl)ethenyl]phenyl]-3-oxopropyl]benzoic acid methyl ester
  • 4-(2-carbomethoxyphenyl)-3-(1-methylethoxy)cyclobut-3-ene-1,2-dione
  • 3-(2-carbomethoxyphenyl)-4-methylcyclobuten-3-ene-1,2-dione 2-(ethylene acetal)
Synthesis Reference(s)Journal of the American Chemical Society, 93, p. 4845, 1971 DOI: 10.1021/ja00748a030
General DescriptionMethyl 2-iodobenzoate can be prepared from 2-iodobenzoic acid via esterification. It undergoes cobalt-catalyzed cyclization with aldehydes to form phthalide derivatives. The microbial dihydroxylation of methyl 2-iodobenzoate forms a nonracemic iodocyclohexene carboxylate intermediate. This intermediate forms the precursor for preparing kibdelone C.
Methyl 2-iodobenzoate Preparation Products And Raw materials
Preparation Products2-Methoxycarbonylphenylboronic acid-->METHYL BIPHENYL-2-CARBOXYLATE-->Methyl 4'-methylbiphenyl-2-carboxylate-->2-Iodobenzyl alcohol-->2,2'-IMINODIBENZOIC ACID-->[R-(E)]-alpha-[3-[2-(7-Chloro-2-quinolinyl)ethenyl]phenyl]-2-(1-hydroxy-1-methylethyl)benzenepropanol-->2-BroMo-5,7-dihydro-7,7-diMethyl-5-phenyl-indeno[2,1-b]carbazole-->Methyl 2-(trifluoromethyl)benzoate-->METHYL 2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZOATE
Methylparaben Methyl 2-bromobenzoate Methyl 2-Iodobenzoic acid Methyl 4-bromobenzoate METHYL 4-IODOBENZOATE,METHYL-P-IODOBENZOATE,Methyl 4-iodobenzoate ,99% Bensulfuron methyl Parathion-methyl 4-Aminobenzoic acid Methyl 4-cyanobenzoate o-Toluic acid Kresoxim-methyl Thiophanate-methyl Methyl benzoate Methyl acrylate Benzoic acid Anthranilic acid Methyl acetate
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