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| | CERIUM(III) CHLORIDE HEPTAHYDRATE Basic information |
| Product Name: | CERIUM(III) CHLORIDE HEPTAHYDRATE | | Synonyms: | Cerium(III) chloride 99,5%;Cerium(III) chloride heptahydrate ,99.99%;CeriuM(III) chloride heptahydrate 99,5%;CeriuM(III) chloride heptahydrate, 99% 100GR;CeriuM(III) chloride heptahydrate, 99% 25GR;CeriuM(III) chloride heptahydrate, 99% 500GR;Ceriumchloridehydrate;Cerium(III) chloride heptahydrate, 99% trace rare earth metals basis | | CAS: | 18618-55-8 | | MF: | CeCl3H14O7 | | MW: | 372.58 | | EINECS: | 606-073-0 | | Product Categories: | Catalysis and Inorganic Chemistry;Ce;Cerium;Cerium Salts;Chemical Synthesis;Isoquinolines ,Quinolines ,Indolines ,Quinaldines;Materials Science;Metal and Ceramic Science;Salts;Ultra-High Purity Materials | | Mol File: | 18618-55-8.mol |  |
| | CERIUM(III) CHLORIDE HEPTAHYDRATE Chemical Properties |
| Melting point | 848 °C | | density | ~3.94 g/mL at 25 °C(lit.) | | storage temp. | Inert atmosphere,Room Temperature | | form | Crystals or Crystalline Powder | | color | Light yellow | | Odor Threshold | Stinging odor | | Water Solubility | Soluble in alcohol, water, and acetone. Slightly soluble in tetrahydrofuran. | | Sensitive | Hygroscopic | | Merck | 14,1997 | | Stability: | Stable, but may be moisture sensitive. Incompatible with strong acids, strong oxidizing agents. | | CAS DataBase Reference | 18618-55-8(CAS DataBase Reference) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36 | | RIDADR | UN 3260 8 / PGIII | | WGK Germany | 3 | | RTECS | FK5100000 | | F | 3-10-21 | | Autoignition Temperature | 400°C | | TSCA | Yes | | HS Code | 28461090 |
| | CERIUM(III) CHLORIDE HEPTAHYDRATE Usage And Synthesis |
| Chemical Properties | colourless crystalline solid | | Uses | Cerium(III) chloride heptahydrate can be used in the conversion of esters to allylsilanes.
| | Uses | Cerium(III) chloride heptahydrate is used in the preparation of allylsilanes from esters. It is used as a reducing agent in organic synthesis in place of sodium borohydride. In Luche reaction, carvone gives selectively allylic alcohol. | | Uses | Catalyst employed in a solvent-free microwave-assisted synthesis of 2-quinolones via condensation of ?-ketoesters with o-anilinoketones. Coupled with NaI promotes the Beckmann rearrangement of oximes. | | General Description | Cerium(III) chloride heptahydrate is a mild Lewis acid. It participates in the allylation of aldehydes. Cerium(III) chloride heptahydrate in combination with sodium iodide supported on silica gel efficiently promotes Michael-type addition. Cerium(III) chloride heptahydrate in the presence of sodium iodide acts as an efficient catalyst for the Michael addition of 1,3-dicarbonyl compounds to α,β-unsaturated ketones and α,β-unsaturated aldehydes. |
| | CERIUM(III) CHLORIDE HEPTAHYDRATE Preparation Products And Raw materials |
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