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Bis(benzonitrile)palladium chloride

Bis(benzonitrile)palladium chloride Basic information
Reaction
Product Name:Bis(benzonitrile)palladium chloride
Synonyms:TRANS-BIS-(BENZONITRILE)PALLADIUM(II) CHLORIDE;Dichlorobis(benzonitrile)palladiuM(II),98% (C6H5CN)2PdCl2;Pd(PhCN)2Cl2;trans-Bis(benzonitrile)palladiuM chloride;Dichlorobis(benzonitrile)palladium(Ⅱ);Benzonitrile, palladium complex;Bis(phenylnitrile)dichloropalladium;Dibenzonitrilepalladium dichloride
CAS:14220-64-5
MF:C14H10Cl2N2Pd
MW:383.57
EINECS:238-085-3
Product Categories:organometallic complexes;Metal Compounds;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Pd (Palladium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;chemical reaction,pharm,electronic,materials;Pd
Mol File:14220-64-5.mol
Bis(benzonitrile)palladium chloride Structure
Bis(benzonitrile)palladium chloride Chemical Properties
Melting point 131 °C(lit.)
storage temp. Inert atmosphere,2-8°C
solubility Soluble in acetone, chloroform
form Crystalline Powder
color Orange to brown
Water Solubility insoluble
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
BRN 3981730
Exposure limitsNIOSH: IDLH 25 mg/m3
InChIInChI=1S/2C7H5N.2ClH.Pd/c2*8-6-7-4-2-1-3-5-7;;;/h2*1-5H;2*1H;/q;;;;+2/p-2
InChIKeyWXNOJTUTEXAZLD-UHFFFAOYSA-L
SMILESC1(C#N)=CC=CC=C1.C1(C#N)=CC=CC=C1.[Pd](Cl)Cl
CAS DataBase Reference14220-64-5(CAS DataBase Reference)
Safety Information
Hazard Codes Xn
Risk Statements 20/21-23/24/25
Safety Statements 22-24/25-23-45-36/37-27-20-9-4
RIDADR UN3439
WGK Germany 3
F 9
TSCA No
HazardClass 6.1
PackingGroup III
HS Code 28439090
MSDS Information
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Bis(benzonitrile)palladium chloride Usage And Synthesis
Reaction
  1. Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides.
  2. Catalyst for the aza-Michael reaction of carbamates with enones.
  3. Catalyst for the rearrangement of allylic imidates to allylic amides.
  4. Catalyst for the Nazarov cyclization of α-alkoxy dienones.
  5. Catalyst for the diamination of conjugated dienes.
  6. Three component Michael addition, cyclization, cross-coupling reaction.
  7. C-H activation of indoles.
Reactions of 14220-64-5_1
Reactions of 14220-64-5_2
Chemical Propertiesyellow powder
Usessuzuki reaction
UsesCatalyst for greener amine synthesis from terminal olefins by Wacker oxidation followed by transfer hydrogenation of the resultant imine.
UsesBis(benzonitrile)palladium(II) chloride can be used as a catalyst:
  • For greener amine synthesis from terminal olefins by Wacker oxidation, followed by transfer hydrogenation of the resultant imine.
  • In cross-coupling reactions and α-O-glycosidation.

Formal anti-Markovnikov hydroamination of terminal olefins
General DescriptionThis product has been enhanced for catalytic efficiency.
Bis(benzonitrile)palladium chloride Preparation Products And Raw materials
Raw materialsToluene-->Palladium chloride-->Benzonitrile
Preparation ProductsChlorodimethylphenylsilane-->1,4-Bis(diphenylphosphino)butane-palladium(II) chloride-->Bis(tricyclohexylphosphine)palladium(II) Dichloride
Methylene Chloride 4-Nitrobenzonitrile Phthalonitrile Calcium chloride Sodium chloride Methyl 4-cyanobenzoate Palladium 4-Aminobenzonitrile Choline chloride 4-Cyanophenol Ammonium chloride Palladium chloride FENBUCONAZOLE 2-Phenylacetoacetonitrile Benzonitrile Potassium chloride 2-Cyanophenol 2-​[[(2-​ethylphenyl)​(2-​hydroxyethyl)​amino]​methyl]​-​3,​3-​difluoro-Propanenitrile
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