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3-Hydroxyphenylboronic acid

3-Hydroxyphenylboronic acid Basic information
Product Name:3-Hydroxyphenylboronic acid
Synonyms:3-Hydroxyphenylboronic Acid (contains varying amounts of Anhydride);3-Hydroxyphenylboronic acid ,98%;3-Hydroxyphenylboronic acid,97%;N-fluorodiphenylsulfonamide;3-Hydroxyphenylboronic acid, May contain varying amounts of anhydride, 97%;m-Hydroxybenzeneboronic acid;3-Hydroxyphenylboronic acid >=95.0%;B-(3-hydroxy-phenyl)boronic acid
CAS:87199-18-6
MF:C6H7BO3
MW:137.93
EINECS:
Product Categories:Substituted Boronic Acids;blocks;BoronicAcids;Boronic Acids & Esters;Boronate Ester;Potassium Trifluoroborate;Phenyls & Phenyl-Het;Organic acids;Boronic Acid;B (Classes of Boron Compounds);Boronic Acids;Boronic Acids & Esters;Phenyls & Phenyl-Het;Boronic Acids;Aryl;Organoborons;Boronic Acids and Derivatives
Mol File:87199-18-6.mol
3-Hydroxyphenylboronic acid Structure
3-Hydroxyphenylboronic acid Chemical Properties
Melting point 210-213 °C (dec.) (lit.)
Boiling point 370.0±44.0 °C(Predicted)
density 1.32±0.1 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
pkapK1:8.55;pK2:10.84 (25°C)
form Crystalline Powder, Crystals and/or Chunks
color Pink to gray to tan
BRN 3240771
InChIKeyWFWQWTPAPNEOFE-UHFFFAOYSA-N
CAS DataBase Reference87199-18-6(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-22
Safety Statements 37/39-26-36/37/39
WGK Germany 3
HazardClass IRRITANT
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
3-Hydroxyphenylboronic acid Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powder
Usessuzuki reaction
Uses3-Hydroxyphenylboronic acid (3-HPBA) can be used as a reagent:
  • In Suzuki-Miyaura coupling reactions with aryl halides for the formation of C-C bond in the presence of Pd catalyst.
  • ?To synthesize boron/nitrogen-doped polymer nano/microspheres by hydrothermal polymerization with formaldehyde and ammonia.??????
  • To prepare carbon quantum dots based on 3-HPBA as selective fructose sensor.?????
  • In the development of modified electrodes for electrochemical biosensors.

3-Hydroxyphenylboronic acid Preparation Products And Raw materials
Preparation Products3-PHENOXYPHENOL-->2-HYDROXY-9-FLUORENONE-->tert-Butyl 4-(3-hydroxybenzylidene)piperidine-1-carboxylate-->3-(3-Hydroxyphenyl)benzyl alcohol
Methylparaben AKOS BRN-1162 4-Hydroxybenzoic acid Ethyl 2-(Chlorosulfonyl)acetate Ascoric Acid 3-Hydroxyphenylboronic acid Folic acid Phenylboronic acid Glycine 4-Hydroxyphenylboronic Acid (contains varying amounts of Anhydride),4-Boronophenol~4-Hydroxyphenylboronic acid,4-HYDROXYPHENYLBORONIC ACID 4-Hydroxybenzaldehyde 2,3,4-Trihydroxybenzoic acid Triclosan 4'-Hydroxyacetophenone 3,5-Dihydroxybenzoic acid 4-Methoxyphenol phosphoric acid Citric acid
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