ChemicalBook Product Catalog Organic Chemistry Phosphines TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE

TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE

TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Basic information
Product Name:TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE
Synonyms:TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE;(E)-1,2-Bis(diphenylphosphino)ethene;[(E)-1,2-Ethenediyl]bis(diphenylphosphine);[(E)-Ethene-1,2-diyl]bis(diphenylphosphine);[(E)-Vinylene]bis(diphenylphosphine);trans-vinylenebis[diphenylphosphine];trans-1,2-Bis(diphenylphosphino)ethylene,97%;NSC 132587
CAS:983-81-3
MF:C26H22P2
MW:396.4
EINECS:213-570-2
Product Categories:Ligand;Phosphine Ligands;Synthetic Organic Chemistry;Catalysis and Inorganic Chemistry;Phosphorus Compounds;Polydentate Phosphine Ligands
Mol File:983-81-3.mol
TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Structure
TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Chemical Properties
Melting point 126-130 °C(lit.)
Boiling point 546.8±33.0 °C(Predicted)
form Crystalline
color White to Almost white
Sensitive Air Sensitive
BRN 757793
CAS DataBase Reference983-81-3(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
RIDADR UN 3464 6.1/PG 2
WGK Germany 3
HS Code 29310099
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
UsesCatalyst for:
  • Coupling of primary and secondary alkyl halides with aryl grignard reagents
  • Homogeneous hydrogenation of Carbon Dioxide mediated by Ruthenium

Reactant for:
  • Preparation of cyclopalladated derivatives of benzylidene
  • Preparation of cyclopalladated complexes containing tridentate thiosemicarbazone ligands as antimalarial agents
  • Catalytic asymetric intramolecular hydroamination of alkynylamines
TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE Preparation Products And Raw materials
trans-1,2-Bis(aminomethyl)cyclobutane 1.1'-Binaphthyl-2.2'-diphemyl phosphine Diphenylphosphine DIPHENYLVINYLPHOSPHINE TRANS-1,2-BIS(DIPHENYLPHOSPHINO)ETHYLENE 1,2-VINYLENEBIS(TRIPHENYLPHOSPHONIUM BROMIDE)
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