ChemicalBook Product Catalog Chemical Reagents Organic reagents Esters Ethyl compound Ethyl α-bromophenylacetate

Ethyl α-bromophenylacetate

Ethyl α-bromophenylacetate Basic information
Product Name:Ethyl α-bromophenylacetate
Synonyms:Phenylbromoacetic acid ethyl ester;α-Bromobenzeneacetic acid ethyl ester;α-Bromophenylacetic acid ethyl ester;Einecs 220-735-2;2-BroMo-2-phenylacetic Acid Ethyl Ester;DL-α-BroMophenylacetic Acid Ethyl Ester;a-Bromophenylacetic acid ethyl ester;ALPHA-BROMOPHENYLACETIC ACID ETHYL ESTER
CAS:2882-19-1
MF:C10H11BrO2
MW:243.1
EINECS:220-735-2
Product Categories:Esters;Phenyls & Phenyl-Het;C10 to C11;Carbonyl Compounds;Pharmaceutical Intermediates
Mol File:2882-19-1.mol
Ethyl α-bromophenylacetate Structure
Ethyl α-bromophenylacetate Chemical Properties
Boiling point 89-92 °C/0.9 mmHg (lit.)
density 1.389 g/mL at 25 °C (lit.)
refractive index n20/D >1.5390(lit.)
Fp >230 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Liquid
color Clear colorless to yellow
Water Solubility Not miscible or difficult to mix in water.
Sensitive Moisture Sensitive
InChIKeyBKTKLDMYHTUESO-UHFFFAOYSA-N
CAS DataBase Reference2882-19-1(CAS DataBase Reference)
EPA Substance Registry SystemEthyl .alpha.-bromophenylacetate (2882-19-1)
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 26-36/37/39-45
RIDADR UN 3265 8/PG 2
WGK Germany 3
HazardClass 8
PackingGroup III
HS Code 29163990
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Ethyl α-bromophenylacetate Usage And Synthesis
Usesα-Bromobenzeneacetic acid ethyl ester is used as an alkyl halide initiator in controlled/living radical polymerization of styrene and methyl methacrylate.
UsesETHYL ALPHA-BROMOPHENYLACETATE is used as an alkyl halide initiator in controlled/living radical polymerization of styrene and methyl methacrylate.
ApplicationEthyl α-bromophenylacetate (EBPA) may be used to synthesize α-ethoxycarbonyl-N,α-diphenylnitrone.
EBPA may be used as an initiator for the following:
polymerization of dimethyl(methacryloyloxymethyl) phosphonate
polymerization of methyl methacrylate (MMA)
polymerization of trimethylolpropane triacrylate(TMPTA)
Synthesis Reference(s)Tetrahedron Letters, 13, p. 4067, 1972 DOI: 10.1016/S0040-4039(01)94239-X
PrecautionsMoisture sensitive. Store away from oxidizing agents, air and water/moisture. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.
Ethyl α-bromophenylacetate Preparation Products And Raw materials
Preparation Productsalpha-Sulfophenylacetic acid-->(4-METHYL-PIPERIDIN-1-YL)-PHENYL-ACETIC ACIDHYDROCHLORIDE-->ETHYL 2-PHENYL-2-PIPERIDINOACETATE
2,3'-Dichloroacetophenone Isopropyl(4-chlorophenyl)acetyl chloride ALPHA-BROMO-1-NAPHTHALENEACETIC ACID ETHYL ESTER PHENYL ACETATE BROMO-(4-FLUORO-PHENYL)-ACETIC ACID ETHYL ESTER A-BROMO-2,4-DICHLOROBENZENEACETIC ACID ETHYL ESTER ETHYL 2-BROMO-2-PHENYLPROPANOATE Ethyl α-bromophenylacetate ALPHA-BROMO-3-CHLOROBENZENEACETIC ACID ETHYL ESTER Ethyl α-bromo-p-chlorophenylacetate ETHYL 2-(3-BROMOPHENYL)ACETATE Ethyl phenylacetate ISOAMYL ALPHA-BROMOPHENYLACETATE Ethyl acetate 2'-BROMO-3,4-DICHLOROPHENYLACETIC ACID METHYL ESTER Bromoacetic acid ETHYL 2-BROMO-(4-BROMOPHENYL)ACETATE
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