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2-Chloroanthraquinone

2-Chloroanthraquinone Basic information
Product Name:2-Chloroanthraquinone
Synonyms:anthraquinone,2-chloro-;β-chloroanthrapuinone;Melting point standard 2-chloroanthraquinone;2-Chloroanthraqukinone;MELTING POINT STANDARD 2-CHLORO- &;2-Chloranthrachinon;2-Chloroanthraquinone,99%;2-Chloroanthraquinone,97%
CAS:131-09-9
MF:C14H7ClO2
MW:242.66
EINECS:205-010-0
Product Categories:API Intermediate;Organics;Electronic Chemicals;Anthraquinones;Chloroanthraquine, etc.;C13 to C14;Intermediates of Dyes and Pigments;Carbonyl Compounds;Ketones
Mol File:131-09-9.mol
2-Chloroanthraquinone Structure
2-Chloroanthraquinone Chemical Properties
Melting point 209-211 °C (lit.)
Boiling point 345.65°C (rough estimate)
density 1.2377 (rough estimate)
refractive index 1.5380 (estimate)
storage temp. Sealed in dry,Room Temperature
form powder to crystal
color White to Light orange to Yellow
Water Solubility insoluble
BRN 2051842
InChIInChI=1S/C14H7ClO2/c15-8-5-6-11-12(7-8)14(17)10-4-2-1-3-9(10)13(11)16/h1-7H
InChIKeyFPKCTSIVDAWGFA-UHFFFAOYSA-N
SMILESC1=C2C(C(=O)C3=C(C2=O)C=CC=C3)=CC=C1Cl
CAS DataBase Reference131-09-9(CAS DataBase Reference)
NIST Chemistry Reference2-Chloroanthraquinone(131-09-9)
EPA Substance Registry System9,10-Anthracenedione, 2-chloro- (131-09-9)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-43-36/37
Safety Statements 26-36-37/39-24
WGK Germany 1
RTECS CB6151000
F 10
TSCA Yes
HS Code 29147090
MSDS Information
ProviderLanguage
2-Chloroanthraquinone English
SigmaAldrich English
ACROS English
ALFA English
2-Chloroanthraquinone Usage And Synthesis
Chemical PropertiesPale yellow needle crystal. Insoluble in water, soluble in hot benzene, nitrobenzene, concentrated sulfuric acid.
Uses2-Chloroanthraquinone is an important dye intermediate that can be used to make alizarin and aminoanthraquinone. This product has been evaluated as a photo-reagent for the analysis of ginsenosides using photoreduction fluorescence (PRF) detection method.
Preparation2-Chloroanthraquinone is prepared by condensing phthalic anhydride and chlorobenzene into p-chlorobenzoylbenzoic acid, and then cyclizing it with sulfuric acid.
Synthesis Reference(s)Tetrahedron Letters, 24, p. 5499, 1983 DOI: 10.1016/S0040-4039(00)94122-4
6,7-DICHLORO-1,4-DIHYDROXYANTHRAQUINONE, 97 2-CHLOROANTHRAQUINONE-3-CARBOXYLIC ACID,3-CHLOROANTHRAQUINONE-2-CARBOXYLIC ACID 1,4-DIAMINO-2-CHLOROANTHRAQUINONE Vat Blue 6 anthraquinone dye(s) 2-CHLORO-1-NITRO-ANTHRAQUINONE 2-amino-3-chloro-anthraquinon 2-Chloroanthraquinone 2-CHLOROQUINIZARIN CHRYSAZIN(RG) Mitoxantrone hydrochloride 2-CHLORO-3-NITRO-ANTHRAQUINONE 2-(BROMOMETHYL)-3-CHLOROANTHRA-9,10-QUINONE Mitoxantrone HCL for Injection (Lyophilized Power) 2-AMINO-1-BROMO-3-CHLOROANTHRAQUINONE 1,3-dichloro-2-methylanthraquinone 2-ACETAMIDO-3-CHLOROANTHRAQUINONE,2-ACETAMINO-3-CHLOROANTHRAQUINONE,2-ACETYLAMINO-3-CHLOROANTHRAQUINONE DITHIANON
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