ChemicalBook Product Catalog Chemical Reagents Organic reagents Cyanide / nitrile 6-BROMOHEXANENITRILE

6-BROMOHEXANENITRILE

6-BROMOHEXANENITRILE Basic information
Product Name:6-BROMOHEXANENITRILE
Synonyms:5-Bromopentyl cyanide;Hexanenitrile, 6-bromo-;6-Bromohexanenitrile,97%;6-Bromocapronitrile,97%;6-BROMOHEXANONITRILE FOR SYNTHESIS;6-Bromohexanenitrile,95%;6-BROMOHEXANENITRILE;6-BROMOCAPRONITRILE
CAS:6621-59-6
MF:C6H10BrN
MW:176.05
EINECS:229-570-0
Product Categories:C6 to C7;Cyanides/Nitriles;Nitrogen Compounds;Building Blocks;C6 to C7;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks
Mol File:6621-59-6.mol
6-BROMOHEXANENITRILE Structure
6-BROMOHEXANENITRILE Chemical Properties
Boiling point 134 °C/13 mmHg (lit.)
density 1.328 g/mL at 25 °C (lit.)
refractive index n20/D 1.477(lit.)
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
solubility Chloroform, Methanol (Slightly)
form Oil
color Colourless
Specific Gravity1.328
BRN 1744172
Exposure limitsNIOSH: IDLH 25 mg/m3
CAS DataBase Reference6621-59-6(CAS DataBase Reference)
EPA Substance Registry SystemHexanenitrile, 6-bromo- (6621-59-6)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
RIDADR 3276
WGK Germany 3
TSCA Yes
HazardClass 6.1
PackingGroup III
HS Code 29269090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
6-BROMOHEXANENITRILE Usage And Synthesis
Chemical Propertiesclear slightly yellow liquid
Uses6-Bromohexanenitrile (6-Bromocapronitrile, 6-Bromohexanonitrile) is suitable reagent used in the synthesis of (5-cyanopentyl)zinc(II) bromide, an organozinc reagent. It may be used in the synthesis of the following:
  • 6-(1,4-dioxa-8-azaspiro[4.5]dec-8-yl)hexanenitrile.
  • dimethyl 6,6′-dithiobiscaproimidate, a long-chain dithiobisimidate.
  • N-benzyloxy-(4-cyanopentyl)-carbamic acid ethyl ester, a N-benzyloxy carbamate derivative.
  • 1-hetarylsulfanyl-ω-cyanoalkanes.
General Description6-Bromohexanenitrile (6-Bromohexanonitrile) is an ω-bromoalkanonitrile. Friedel Crafts alkylation of 6-bromohexanenitrile with benzene has been studied.
RARECHEM AQ BC 9054 2,2-DIMETHYL-6-BROMOHEXANENITRILE RARECHEM AQ TC 8010 RARECHEM AQ BC 9100 2,6-DIBROMO-4,8-DICYANOTRICYCLO[3.3.1.0(1,5)]NONA-3,7-DIENE 6-BROMOHEXANENITRILE RARECHEM AQ TC 8013 RARECHEM AQ BC 8114 RARECHEM AQ TC 8018 RARECHEM AQ BC 8116 4,8-DIBROMOBICYCLO[3.3.1]NONA-2,6-DIENE-2,6-DICARBONITRILE HEXANENITRILE 1,4-DIBROMOPENTACYCLO[4.3.0.0(2,5).0(3,8).0(4,7)]NONANE-9-CARBONITRILE RARECHEM AQ BC 8100 RARECHEM AQ TC 9011 (1-BROMOSPIRO(PENTACYCLO[4.3.0.0(2,4).0(3,8).0(5,7)]NONANE-9,2'-[1,3]-DIOXOLANE)-4-YL)ACETONITRILE RARECHEM AQ TC 8016 6-Bromohept-6-enenitrile
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