FMOC-L-Methionine

FMOC-L-Methionine Basic information

Product Name:	FMOC-L-Methionine
Synonyms:	FMOC-L-MET;FMOC-L-METHIONINE;FMOC-L-MET-OH;N-ALPHA-FMOC-L-METHIONINE;N-(9-FLUORENYLMETHOXYCARBONYL)-L-METHIONINE;N-[(9H-FLUOREN-9-YLMETHOXY)CARBONYL]-L-METHIONINE;N-9-FLUORENYLMETHYLOXYCARBONYL-L-METHIONINE;N-ALPHA-(9-FLUORENYLMETHYLOXYCARBONYL)-L-METHIONINE
CAS:	71989-28-1
MF:	C20H21NO4S
MW:	371.45
EINECS:	276-258-5
Product Categories:	Methionine [Met, M];Fmoc-Amino Acids and Derivatives;Amino Acids (N-Protected);Biochemistry;Nutritional Supplements;Fmoc-Amino acid series;Protected Amino Acids;Fluorenes, Flurenones;Amino Acids;Fmoc-Amino Acids
Mol File:	71989-28-1.mol

FMOC-L-Methionine Chemical Properties

Melting point	121-123 °C(lit.)
alpha	-29 º (c=1,DMF 24 ºC)
Boiling point	614.6±55.0 °C(Predicted)
density	1.2053 (rough estimate)
refractive index	-29.5 ° (C=1, DMF)
storage temp.	2-8°C
solubility	very faint turbidity in Methanol
pka	3.72±0.10(Predicted)
form	Granular Powder
color	White
optical activity	[α]20/D -29.5±1.5°, c = 1% in DMF
BRN	4300266
InChI	InChI=1S/C20H21NO4S/c1-26-11-10-18(19(22)23)21-20(24)25-12-17-15-8-4-2-6-13(15)14-7-3-5-9-16(14)17/h2-9,17-18H,10-12H2,1H3,(H,21,24)(H,22,23)/t18-/m0/s1
InChIKey	BUBGAUHBELNDEW-SFHVURJKSA-N
SMILES	C(O)(=O)[C@H](CCSC)NC(OCC1C2=C(C=CC=C2)C2=C1C=CC=C2)=O
CAS DataBase Reference	71989-28-1(CAS DataBase Reference)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	22-24/25-36/37/39-27-26
WGK Germany	3
HS Code	2930 90 98

MSDS Information

Provider	Language
FMOC-L-Methionine	English
ACROS	English
SigmaAldrich	English
ALFA	English

FMOC-L-Methionine Usage And Synthesis

Chemical Properties	white to light yellow crystal powde
Uses	N-Fmoc-L-methionine is an N-Fmoc-protected form of L-Methionine (M260440). L-Methionine is an essential amino acid that is obtained from our diet. L-Methionine can be found in grain legumes (such as lentils), and poultry. L-Methionine’s main function is to act as the primary “Start” sequence on mRNA so that the ribosomes can start translating the mRNA into proteins.

FMOC-L-Methionine Preparation Products And Raw materials

Raw materials	1H-Benzotriazole-1-carboxylic acid, 9H-fluoren-9-ylmethyl ester-->methyl (2S)-2-(9H-fluoren-9-ylmethoxycarbonylamino)-4-methylsulfanylbutanoate-->FMoc-DL-Methionine-->9-FLUORENYLMETHYL PENTAFLUOROPHENYL CARBONATE-->N-(9-Fluorenylmethoxycarbonyloxy)succinimide-->9-Fluorenylmethyl chloroformate-->L-Methionine
Preparation Products	BOC-L-Methionine-->H-MET-NH2

1,1'-Carbonyldiimidazole Zinc methionine sulfate N-alpha-FMOC-Nepsilon-BOC-L-Lysine Fmoc-Asp(OtBu)-OH N-ALPHA-FMOC-L-METHIONINE-SULFONE,FMOC-L-METHIONINE-SULFONE FMOC-L-Methionine Fmoc-Aib-OH N-ALPHA-FMOC-L-METHIONINE PENTAFLUOROPHENYL ESTER,FMOC-L-METHIONINE PENTAFLUOROPHENYL ESTER CARBONYL SULFIDE L-Fmoc-Aspartic acid alpha-tert-butyl ester FMOC-MET-2-CL-TRT RESIN NICKEL CARBONYL DL-Methionine 9-Fluorenylmethyl chloroformate (2S,4R)-FMOC-4-TRITYLMERCAPTO-PYRROLIDINE-2-CARBOXYLIC ACID FMOC-L-BUTHIONINE N-ALPHA-FMOC-L-METHIONINE-DL-SULFOXIDE,FMOC-L-METHIONINE-DL-SULFOXIDE,N-ALPHA-FMOC-L-METHIONINE-SULFOXIDE,FMOC-L-METHIONINE SULFOXIDE N-(9-Fluorenylmethoxycarbonyloxy)succinimide

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