ChemicalBook Product Catalog Chemical Reagents Organic reagents Boric acid 4-Fluoro-3-methylphenylboronic acid

4-Fluoro-3-methylphenylboronic acid

4-Fluoro-3-methylphenylboronic acid Basic information
Product Name:4-Fluoro-3-methylphenylboronic acid
Synonyms:4-FLUORO-3-METHYLPHENYLBORONIC ACID;4-FLUORO-M-TOLYLBORONIC ACID;3-METHYL-4-FLUOROPHENYLBORONIC ACID;AKOS BRN-0103;RARECHEM AH PB 0182;Boronic acid, (4-fluoro-3-methylphenyl)- (9CI);4-Fluoro-3-methylphenylboronicacid~4-Fluoro-m-tolylboronicacid;4-Fluoro-3-methylphenylboronic Acid (contains varying amounts of Anhydride)
CAS:139911-27-6
MF:C7H8BFO2
MW:153.95
EINECS:640-290-1
Product Categories:Organoborons;Boronic acid;Aryl;Boronic Acids;Boronic Acids and Derivatives;HALIDE;blocks;BoronicAcids;FluoroCompounds;Boronic Acid series;Fluorin-contained phenyl boronic acid series
Mol File:139911-27-6.mol
4-Fluoro-3-methylphenylboronic acid Structure
4-Fluoro-3-methylphenylboronic acid Chemical Properties
Melting point 212-217 °C (lit.)
Boiling point 282.0±50.0 °C(Predicted)
density 1.20±0.1 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
pka8.71±0.10(Predicted)
form Crystalline Powder
color White to off-white
BRN 7474834
CAS DataBase Reference139911-27-6(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36/37/39-27-37/39
WGK Germany 3
HazardClass IRRITANT
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
4-Fluoro-3-methylphenylboronic acid Usage And Synthesis
Chemical PropertiesOff-white Cryst
UsesReactant for:
  • Preparation of lipophilic-tailed monocationic inhibitors of neuronal nitric oxide synthase
  • Stereoselective desymmetrizing rhodium-catalyzed allylic arylation
  • Solvent free catalytic C-H functionalization reactions
  • Homocoupling reactions
  • Suzuki-Miyaura cross-coupling and Heck reactions under air
Usessuzuki reaction
4-Fluoro-3-methylphenylboronic acid Preparation Products And Raw materials
Preparation Products2-Fluoro-5-nitrotoluene-->2-(4-FLUORO-3-METHYLPHENYL)PYRIDINE-->4-(4-Fluoro-3-methylphenyl)benzyl alcohol
5-CHLORO-2-FLUORO-3-METHYLPHENYLBORONIC ACID 3-(BENZYLCARBAMOYL)-4-FLUOROBENZENEBORONIC ACID 2,4-DIFLUORO-3-FORMYLPHENYLBORONIC ACID 4-FLUORO-3-(TRIFLUOROMETHYL)PHENYLBORONIC ACID 3-(DIETHYLCARBAMOYL)-4-FLUOROBENZENEBORONIC ACID 3-(2-FLUORO-5-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENYL)PYRIDINE 3-FLUORO-2-METHYLPHENYLBORONIC ACID 3-(TERT-BUTYLCARBAMOYL)-4-FLUOROBENZENEBORONIC ACID 3-(DIMETHYLCARBAMOYL)-4-FLUOROBENZENEBORONIC ACID 5-Bromo-2-fluoro-3-methylphenylboronic acid 4-FLUORO-3-(METHYLCARBAMOYL)BENZENEBORONIC ACID 4-FLUORO-2-METHYLPHENYLBORONIC ACID, PINACOL ESTER 3-(ETHYLCARBAMOYL)-4-FLUOROBENZENEBORONIC ACID 3-(N-BUTYLCARBAMOYL)-4-FLUOROBENZENEBORONIC ACID 2-Bromo-6-fluoro-3-methylphenylboronic acid 3-Bromo-2-fluoro-5-methylphenylboronic acid 2-CHLORO-6-FLUORO-3-METHYLPHENYLBORONIC& 3-Cyano-4-fluorobenzeneboronic acid
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