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| | 2-METHYL-1-PHENYLPROPENE Basic information |
| Product Name: | 2-METHYL-1-PHENYLPROPENE | | Synonyms: | ISOCROTYLBENZENE;(2-methyl-1-propenyl)-benzen;(2-Methyl-1-propenyl)benzene;1,1-Dimethyl-2-phenylethylene;(2-METHYLPROPENYL)BENZENE;2-METHYL-1-PHENYL-1-PROPENE;2-METHYL-1-PHENYLPROPENE;Methylphenylpropene | | CAS: | 768-49-0 | | MF: | C10H12 | | MW: | 132.2 | | EINECS: | 212-194-6 | | Product Categories: | Propanes/propenes | | Mol File: | 768-49-0.mol |  |
| | 2-METHYL-1-PHENYLPROPENE Chemical Properties |
| Melting point | -50--48 °C (lit.) | | Boiling point | 187-188 °C (lit.) | | density | 0.901 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.539(lit.) | | Fp | 138 °F | | storage temp. | 2-8°C | | solubility | Chloroform (Soluble), Methanol (Slightly) | | form | clear liquid | | color | Colorless to Almost colorless | | BRN | 1902046 | | CAS DataBase Reference | 768-49-0(CAS DataBase Reference) | | EPA Substance Registry System | (2-Methyl-1-propenyl)benzene (768-49-0) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36 | | RIDADR | UN 3295 3/PG 3 | | WGK Germany | 3 | | HazardClass | 3.2 | | PackingGroup | III | | HS Code | 2902900000 |
| | 2-METHYL-1-PHENYLPROPENE Usage And Synthesis |
| Uses | 2-Methyl-1-phenyl-1-propene has been used in the preparation of 2-bromo-2-methyl-1-phenylpropan-1-ol and 1-bromo-2-methyl-1-phenylpropan-2-ol. | | Synthesis Reference(s) | Journal of the American Chemical Society, 111, p. 3069, 1989 DOI: 10.1021/ja00190a053
Tetrahedron Letters, 25, p. 271, 1984 DOI: 10.1016/S0040-4039(00)99859-9
The Journal of Organic Chemistry, 55, p. 5619, 1990 DOI: 10.1021/jo00308a021 |
| | 2-METHYL-1-PHENYLPROPENE Preparation Products And Raw materials |
| Raw materials | Benzene, [(1Z)-2-chloro-1-propen-1-yl]--->DICHLOROSTYRENE-->ISOPROPYLTRIPHENYLPHOSPHONIUM IODIDE-->1-CHLORO-2-METHYL-1-PROPENE-->Benzene,(1-chloro-2-methylpropyl)--->2-METHYL-1-PHENYL-1-PROPANOL-->3-HYDROXY-2,2-DIMETHYL-3-PHENYLPROPIONIC ACID, 99-->Isobutyrophenone-->(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE-->Benzaldehyde | | Preparation Products | 2-METHYL-3-PHENYL-1-PROPENE-->Isobutylbenzene-->ISOBUTYLCYCLOBUTANE-->2-BROMO-2-METHYLPROPIOPHENONE-->2,2-diMethyl-3-phenyloxirane |
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