2-Bromobenzoic acid

2-Bromobenzoic acid Basic information

Product Name:	2-Bromobenzoic acid
Synonyms:	o-bromo-benzoicaci;2-Bromobenzoic aicd;2-bromo-benzoicaci;Benzoic acid, o-bromo-;benzoicacid,2-bromo-;bromobenzoicacid;2-Brom-benzoic acid;Brombenzoicacid,95%
CAS:	88-65-3
MF:	C7H5BrO2
MW:	201.02
EINECS:	201-848-6
Product Categories:	Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts;Benzoic acid;Organic acids;Acids & Esters;Bromine Compounds;C7;Carbonyl Compounds;Carboxylic Acids;alkyl bromide\| carboxylic acid;Aromatic Compounds;bc0001
Mol File:	88-65-3.mol

2-Bromobenzoic acid Chemical Properties

Melting point	147-150 °C (lit.)
Boiling point	86 °C(Press: 4-5 Torr)
density	1,929 g/cm³
vapor pressure	>1 mm Hg ( 20 °C)
refractive index	1.6080 (estimate)
Fp	>100°C
storage temp.	Sealed in dry,Room Temperature
solubility	95% ethanol: soluble100mg/mL, clear, colorless to yellow
pka	2.84(at 25℃)
form	Powder
color	White to light yellow or beige
Water Solubility	slightly soluble
BRN	971266
InChIKey	XRXMNWGCKISMOH-UHFFFAOYSA-N
CAS DataBase Reference	88-65-3(CAS DataBase Reference)
NIST Chemistry Reference	Benzoic acid, 2-bromo-(88-65-3)
EPA Substance Registry System	2-Bromobenzoic acid (88-65-3)

Safety Information

Hazard Codes	Xi,Xn
Risk Statements	36/37/38-36-37/38-22
Safety Statements	26-36-24/25-37/39
WGK Germany	3
RTECS	DG4448035
Hazard Note	Irritant
TSCA	Yes
HS Code	29163900

MSDS Information

Provider	Language
2-Bromobenzoic acid	English
SigmaAldrich	English
ACROS	English
ALFA	English

2-Bromobenzoic acid Usage And Synthesis

Chemical Properties	White to light yellow crystal powder
Uses	2-Bromobenzoic acid was used in the synthesis of new zinc(II) ? 2-bromobenzoate complex compounds. It was used as the starting reagent in the synthesis of hemilabile benzimidazolyl phosphine ligands.
Synthesis Reference(s)	Canadian Journal of Chemistry, 43, p. 1306, 1965 DOI: 10.1139/v65-178 The Journal of Organic Chemistry, 59, p. 4042, 1994 DOI: 10.1021/jo00094a007
General Description	2-Bromobenzoic acid (2-BA) on condensation with aminoquinolines yields phenylquinolylamines. 2-BA is the common building block for synthesis of various nitrogen heterocycles.
Purification Methods	Crystallise the acid from *C6H6 or MeOH. The anilide has m 141o (from EtOH/H2O). [Beilstein 9 IV 1011.]

2-Bromobenzoic acid Preparation Products And Raw materials

Raw materials

Oxygen-->2-Bromotoluene

Preparation Products

2-BROMO-5-NITROBENZOIC ACID-->4-CHLORO-2-PHENYLQUINAZOLINE-->2-PHENYL-4-[3H]QUINAZOLINONE-->Triphenylene-->Methyl 2-bromobenzoate-->tert-Butyl 4'-(bromomethyl)biphenyl-2-carboxylate-->2-Bromobenzyl bromide-->Methoxymethyldiphenylamine-->9-Chloroacridine-->Benzoic acid, 2-ethenyl- (9CI)-->2-Bromo-3-nitrobenzoic acid-->2,2'-IMINODIBENZOIC ACID-->2-Biphenylcarboxylic acid-->1(3H)-Isobenzofuranone,3-methyl-(9CI)-->[R-(E)]-alpha-[3-[2-(7-Chloro-2-quinolinyl)ethenyl]phenyl]-2-(1-hydroxy-1-methylethyl)benzenepropanol-->5H-Dibenz[b,f]azepine-10,11-dione-->2-(2-Bromophenyl)-2-propanol-->3,3-dimethylphthalide

2-[(2-Nitrophenyl)thioamino]-5-bromobenzoic acid 2-[[(4-Methylphenyl)oxy]acetylamino]-5-bromobenzoic acid 2-Bromobenzoic acid succinimidyl ester (-)-m-Bromobenzoic acid (R)-2-methylbutyl ester 4-Acetylamino-3-bromobenzoic acid methyl ester 3-Nitro-2-bromobenzoic acid methyl ester 2-Chloro-6-bromobenzoic acid Ethyl 2-(Chlorosulfonyl)acetate 3-Bromobenzoic acid bromide Tetrabromo-2-sulfobenzoic acid cyclic anhydride (-)-p-Bromobenzoic acid (R)-2-methylbutyl ester t-Butyl-6-Bromo-2,3-dimethoxybenzoic acid 2-Hydroxy-3-formyl-5-bromobenzoic acid 4-[6-(2-Ethylhexanoylamino)-1H-indol-1-yl]-2-bromobenzoic acid phosphoric acid 4-Bromobenzoic acid phenacyl ester 4-Nitro-3-bromobenzoic acid methyl ester 3,3'-(Terephthaloyldiimino)bis(4-bromobenzoic acid)

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