ChemicalBook Product Catalog Chemical Reagents Organic reagents Fatty alcohols 2-METHYL-1-PENTANOL

2-METHYL-1-PENTANOL

2-METHYL-1-PENTANOL Basic information
Product Name:2-METHYL-1-PENTANOL
Synonyms:2-Methylamyl Alcohol;2-Methyl-1-pentanol, 98.5+%;methylpentanol(non-specificname);sec-amylcarbinol;Amyl methyl alcohol;2-METHYL-N-AMYL ALCOHOL;2-Methyl-1-penmnol;2-METHYL-1-PENTANOL
CAS:105-30-6
MF:C6H14O
MW:102.17
EINECS:203-285-1
Product Categories:Alcohols;C2 to C6;Oxygen Compounds
Mol File:105-30-6.mol
2-METHYL-1-PENTANOL Structure
2-METHYL-1-PENTANOL Chemical Properties
Melting point -48.42°C (estimate)
Boiling point 148 °C(lit.)
density 0.824 g/mL at 25 °C(lit.)
vapor density 3.5 (vs air)
vapor pressure 1.5 mm Hg ( 20 °C)
refractive index n20/D 1.418(lit.)
Fp 123 °F
storage temp. 2-8°C
pka15.05±0.10(Predicted)
form Liquid
color Colorless to Almost colorless
explosive limit9.6%
Water Solubility 5.96g/L(25 ºC)
BRN 1718974
LogP1.702 (est)
CAS DataBase Reference105-30-6(CAS DataBase Reference)
EPA Substance Registry System2-Methyl-1-pentanol (105-30-6)
Safety Information
Hazard Codes Xn
Risk Statements 10-22
Safety Statements 24/25
RIDADR UN 1987 3/PG 3
WGK Germany 3
RTECS SA7175000
HS Code 2905.14.5010
HazardClass 3.2
PackingGroup III
Hazardous Substances Data105-30-6(Hazardous Substances Data)
ToxicityLD50 orl-rat: 1410 mg/kg AMIHBC 10,61,54
MSDS Information
ProviderLanguage
SigmaAldrich English
2-METHYL-1-PENTANOL Usage And Synthesis
Chemical PropertiesCLEAR COLOURLESS LIQUID
UsesSolvent, intermediate.
Production Methods2-Methyl-1-pentanol is prepared by the aldol condensation of propionaldehyde and subsequent hydrogenation of the intermediate 2-methyl-2-pentanol. Commercially, the methyl- 1-pentanols are rarely used alone but as amixture.
Synthesis Reference(s)Journal of the American Chemical Society, 77, p. 6052, 1955 DOI: 10.1021/ja01627a077
General DescriptionNonaqueous lipase-catalyzed kinetic resolution of racemic 2-methyl-1-pentanol in a continuously operated fixed bed reactor has been reported. Molar excess enthalpies of binary mixtures of 2-methyl-1-pentanol with n-hexane and its isomers has been measured in a flow microcalorimeter.
HazardModerate fire risk.
Safety ProfileModerately toxic by ingestion and skin contact. A skin and severe eye irritant. Human systemic irritant by inhalation. A flammable liquid; can react with oxidizing materials. To fight fire, use Con, dry chemical. When heated to decomposition it emits smoke and acrid fumes.
Purification MethodsDry the 1-pentanol with Na2SO4 and distil it. [Beilstein 1 IV 1713.]
2-METHYL-1-PENTANOL Preparation Products And Raw materials
Preparation ProductsMethyl valeraldehyde-->2-METHYL-2-PENTANOL-->Tetrahydrofuran
(3S)-3-Methyl-1-pentanol (-)-TRANS-MYRTANOL 5-Methoxy-2-methyl-2-pentanol 5-[[(4-Methyl-3,4,5,6-tetrahydro-2H-pyran)-2-yl]oxy]-3-methyl-1-pentanol 2,2'-Azobis(4-methyl-2-pentanol)diacetate METHYL O-METHYLPODOCARPATE [S,(+)]-2-Methyl-3-pentanol 3,5-dinitrobenzoate (2S,3R)-3-Chloro-4-methyl-2-pentanol (2S)-2-[[N-[(2S)-2-[(Benzyloxycarbonyl)amino]-3-(naphthalen-1-yl)propionyl]-L-histidyl]amino]-4-methyl-1-pentanol AURORA KA-477 cis-VERBENOL 1-(4-METHOXYPHENYL)-1-CYCLOPENTANECARBOXYLIC ACID Cycloleucine DL-ISOPINOCAMPHEOL [R,(-)]-2-Methyl-3-pentanol 3,5-dinitrobenzoate ALPHA-PHENYLCYCLOPENTANEACETIC ACID [R,(-)]-4-Methyl-2-pentanol N-(1-naphtyl)carbamate 1,2,3,4-CYCLOPENTANETETRACARBOXYLIC ACID
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