4-Bromobenzyl bromide

4-Bromobenzyl bromide Basic information

Product Name:	4-Bromobenzyl bromide
Synonyms:	A,P-DIBROMOTOLUENE;,4-Dibromotoluene;1-bromo-4-(bromomethyl)-benzen;p,-Dibromotoluene;AKOS BBS-00004014;ALPHA,P-DIBROMOTOLUENE;ALPHA,4-DIBROMOTOLUENE;4-BROMOBENZYL BROMIDE
CAS:	589-15-1
MF:	C7H6Br2
MW:	249.93
EINECS:	209-636-5
Product Categories:	alkyl bromide;C7;Chemical Synthesis;Halogenated Hydrocarbons;Organic Building Blocks;Benzyl;Aryl;Building Blocks;Miscellaneous;Methyl Halides;Phenyls & Phenyl-Het;Aromatic Halides (substituted);Methyl Halides;Phenyls & Phenyl-Het;bc0001
Mol File:	589-15-1.mol

4-Bromobenzyl bromide Chemical Properties

Melting point	62-64 °C(lit.)
Boiling point	115-124 °C (12 mmHg)
density	1.8246 (rough estimate)
refractive index	1.6066 (estimate)
Fp	115-124°C/12mm
storage temp.	Keep in dark place,Inert atmosphere,2-8°C
form	Coarse Crystalline Solid or Solid Melt
color	White to tan
Water Solubility	MAY DECOMPOSE
Sensitive	Lachrymatory
Merck	14,1409
BRN	606498
CAS DataBase Reference	589-15-1(CAS DataBase Reference)
EPA Substance Registry System	Benzene, 1-bromo-4-(bromomethyl)- (589-15-1)

Safety Information

Hazard Codes	C
Risk Statements	34-42/43
Safety Statements	22-26-36/37/39-45-25
RIDADR	UN 3261 8/PG 2
WGK Germany	3
F	19
Hazard Note	Corrosive/Lachrymatory
TSCA	T
HazardClass	8
PackingGroup	III
HS Code	29036990

MSDS Information

Provider	Language
alpha,4-Dibromotoluene	English
SigmaAldrich	English
ACROS	English
ALFA	English

4-Bromobenzyl bromide Usage And Synthesis

Chemical Properties	White solid
Uses	Identification of aromatic carboxylic acids.
Uses	4-Bromobenzyl bromide is used to prepare a 20-member aminomethyl-substituted biaryl library via sequential N-alkylation of various amines.
Synthesis Reference(s)	Synthetic Communications, 11, p. 669, 1981 DOI: 10.1080/00397918108063642
Purification Methods	Crystallise the bromide from EtOH. [Beilstein 5 IV 836.] LACHRYMATORY.

4-Bromobenzyl bromide Preparation Products And Raw materials

Raw materials	Potassium bromide-->4-Bromotoluene-->Dibromomethane
Preparation Products	1-(4-BROMOBENZYL)PIPERAZINE-->4-Bromobenzylamine-->TRIMETHYLGERMANIUM BROMIDE-->3-(4-Bromophenyl)propionic acid-->6-Bromoindanone-->4-BROMODIPHENYLMETHANE-->6-BROMO-2,3-DIHYDRO-1H-INDEN-1-OL-->1,3-Bis(4-bromophenyl)propanone-->DIETHYL 4-BROMOBENZYL PHOSPHONATE

4-BROMO-4'-N-PENTYLBIPHENYL 4-(BROMOMETHYL)-BENZOIC ACID, 1,1-DIMETHYLETHYL ESTER 4-BROMOBENZHYDROL p-(2-Bromoethyl)anilineHydrochloride 4-Bromobenzoic acid Rocuronium bromide 4-Methoxybenzylchloride 3-Bromo-2-methoxy-5-trifluoromethylpyridine 2-Fluoro-5-bromobenzyl bromide 2-Fluoro-6-bromobenzyl bromide M-BROMOBENZYL BROMIDE,3-BROMOBENZYL BROMIDE,3-Bromo Benzyl Bromide m-Bromobenzyl Bromide 4-Fluorobenzyl chloride BENZAL BROMIDE 4-BROMOBENZYL BROMIDE, [7-14C] 4-Bromobenzyl bromide 4-Bromobenzylamine 3-Fluoro-5-bromobenzyl bromide 4-Chlorobenzyl chloride

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