ChemicalBook Product Catalog Chemical Reagents Organic reagents Acyl halide CHLOROCARBONYLSULFENYL CHLORIDE

CHLOROCARBONYLSULFENYL CHLORIDE

CHLOROCARBONYLSULFENYL CHLORIDE Basic information
Product Name:CHLOROCARBONYLSULFENYL CHLORIDE
Synonyms:Chloroformylsulfenyl Chloride Chlorothioformyl Chloride;Chlorocarbonylsulfenyl chloride 96%;(Chlorothio)formyl chloride, Chloroformylsulfenyl chloride;(Chloroformyl)sulfur chloride;1-(Chlorothio)formic acid chloride;Chlorocarbonylthio chloride;Chloroformic hypochlorous thioanhydride;Chloroformyl thiohypochlorite
CAS:2757-23-5
MF:CCl2OS
MW:130.98
EINECS:220-415-2
Product Categories:Sulfur Compounds (for Synthesis);Synthetic Organic Chemistry
Mol File:2757-23-5.mol
CHLOROCARBONYLSULFENYL CHLORIDE Structure
CHLOROCARBONYLSULFENYL CHLORIDE Chemical Properties
Boiling point 98 °C (lit.)
density 1.552 g/mL at 25 °C (lit.)
refractive index n20/D 1.517(lit.)
Fp 98-101°C
storage temp. 2-8°C
solubility Acetonitrile (Slightly), Chloroform (Sparingly)
form Liquid, Fuming In Moist Air
color Yellow
Sensitive Moisture Sensitive
BRN 506318
Stability:Moisture Sensitive
CAS DataBase Reference2757-23-5(CAS DataBase Reference)
Safety Information
Hazard Codes C
Risk Statements 34-37
Safety Statements 26-36/37/39-45
RIDADR UN 3265 8/PG 2
WGK Germany 3
F 9-13-21
HazardClass 8
PackingGroup II
HS Code 29309090
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
CHLOROCARBONYLSULFENYL CHLORIDE Usage And Synthesis
Chemical PropertiesYellow liquid, fuming in moist air
UsesChlorocarbonylsulfenyl chloride has been used in the preparation of:
  • 5-(1,2,3,4-tetra-O-acetyl-alpha-D-xylopyranos-5S-C-yl)-1,3,4-oxathiazol-2-one
  • fluorinated oxathialones
  • polyfluoroalkylchlorothioformates
  • chlorocarbonylpolyfluoroalkylsulfenate esters
  • chlorocarbonylhexafluoroisopropylidenimino sulfenate
  • 5-tri-fluoromethyl-2-oxo-1,3,4-oxathiazole
  • commercially important N,N-dialkylcarbamoyl chlorides
CHLOROCARBONYLSULFENYL CHLORIDE Preparation Products And Raw materials
Preparation Products4-Morpholinecarbonyl chloride-->5-(4-METHOXYPHENYL)-1,3,4-OXATHIAZOL-2-ONE-->ETHYL 2-OXO-4-(TRIFLUOROMETHYL)-2,3-DIHYDRO-1,3-THIAZOLE-5-CARBOXYLATE
4-CHLOROPHENYL CHLOROTHIONOFORMATE 3-Fluoro-4-methylphenylisothiocyanate methyl 4-(chlorocarbonothioyloxy)benzoate 4-(trifluoromethoxy)phenyl chlorothioformate 2-BROMO-4-FLUOROPHENYL CHLOROTHIOFORMATE o-5,6,7,8-Tetrahydro-2-naphtylthiochloroformate 1,4-PHENYLENE DIISOTHIOCYANATE N-TERT-BUTYLBENZENESULFENAMIDE Phenyl chlorothionocarbonate PENTAFLUOROPHENYL CHLOROTHIONOFORMATE Crotonic acid 3,5-DIMETHYLPHENYL CHLOROTHIOFORMATE 2,4-DICHLOROPHENYL CHLOROTHIOFORMATE Hydrogen Sulfide Sulfuryl chloride METHYL MERCAPTAN CHLOROCARBONYLSULFENYL CHLORIDE Sulphur
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