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| | NITROCYCLOPENTANE Basic information |
| | NITROCYCLOPENTANE Chemical Properties |
| Melting point | 143-144 °C | | Boiling point | 180 °C (lit.) | | density | 1.086 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.454(lit.) | | Fp | 153 °F | | pka | 8.46±0.20(Predicted) | | BRN | 907079 | | CAS DataBase Reference | 2562-38-1 |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36/37/39 | | RIDADR | 2810 | | WGK Germany | 3 | | RTECS | GY4657500 | | HazardClass | 6.1 | | PackingGroup | III | | HS Code | 29042000 |
| | NITROCYCLOPENTANE Usage And Synthesis |
| Chemical Properties | Clear pale yellow liquid | | Preparation | Bromocyclopentane (22.0 g, 0.15 mol) was added to a soln of NaNO2 (18 g, 0.26 mol) in dry DMSO (100 mL) at 15 ℃ and the mixture was stirred at this temperature for 3 h. The mixture was poured into ice water (250 mL) and extracted with petroleum ether (bp 35-37 ℃; 4 × 50 mL). The combined organic extracts were washed with H2O (4× 50 mL), dried (MgSO4), and concentrated under reduced pressure. The residue was distilled to give Nitrocyclopentane; yield: 9.9 g (58%); bp 62 ℃/8 Torr; nD/20 1.4538.
Synthesis of Nitrocyclopentane | | Synthesis Reference(s) | Tetrahedron Letters, 21, p. 1117, 1980 DOI: 10.1016/S0040-4039(01)83928-9 | | General Description | Nitrocyclopentane, a secondary nitroalkane, was examined for its ability to induce DNA repair in rat hepatocytes. The nitronate of nitrocyclopentane was mutagenic in Salmonella strains TA100 and TA102. |
| | NITROCYCLOPENTANE Preparation Products And Raw materials |
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