Bismuth(III) trifluoromethanesulfonate

Bismuth(III) trifluoromethanesulfonate Basic information
Uses
Product Name:Bismuth(III) trifluoromethanesulfonate
Synonyms:BISMUTH(III)TRIFLATE;BISMUTH(III) TRIFLUOROMETHANESULFONATE;BISMUTH(III)TRIFLUOROMETHANESULPHONATE;BISMUTH TRIFLATE;BISMUTH TRIFLUOROMETHANESULFONATE HYDRATE;BISMUTH TRIFLUOROMETHANESULFONATE, ANHY&;Trifluoromethanesulfonicacidbismuthsalt;Bismuth(III)trifluoromethanesulfonate,min.98%(Bismuthtriflate)
CAS:88189-03-1
MF:3CF3O3S.Bi
MW:656.18
EINECS:
Product Categories:metal triflate compound;triflate;Bismuth;Catalysis and Inorganic Chemistry;Chemical Synthesis
Mol File:88189-03-1.mol
Bismuth(III) trifluoromethanesulfonate Structure
Bismuth(III) trifluoromethanesulfonate Chemical Properties
Melting point 300 °C
storage temp. Inert atmosphere,Room Temperature
solubility Soluble in organics acetonitrile, dioxane, dimethyl formamide and dimethyl sulfoxide.
form Liquid
color Clear colorless
Sensitive Hygroscopic
Hydrolytic Sensitivity5: forms reversible hydrate
Stability:hygroscopic
InChIKeyHIYUMYXSGIKHHE-UHFFFAOYSA-M
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-24/25
WGK Germany 3
Hazard Note Irritant
TSCA No
HazardClass 8
HS Code 29049090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Bismuth(III) trifluoromethanesulfonate Usage And Synthesis
UsesBismuth(III) trifluoromethanesulfonate is powerful Lewis acid useful in a number of catalytic reactions. 
Chemical PropertiesWhite powder
UsesCatalyst for organic syntheses.
UsesBismuth(III) trifluoromethanesulfonate acts as a catalyst in Friedel-Crafts acylation and cycloisomerization of allene-enol ethers. It behaves as a direct substitution catalyst and involved in the substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carboxamides and carbamates. Further, it is also used in Mukaiyama aldol reactions.
UsesCatalyzes direct substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carbamates, and carboxamides.
Bismuth(III) trifluoromethanesulfonate Preparation Products And Raw materials
BISMUTH(III) BROMIDE BISMUTH TELLURIDE BISMUTH TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE) BISMUTH(III) IODIDE BISMUTH ACETATE BISMUTH(III) FLUORIDE Bismuth trichloride BISMUTH NEODECANOATE BISMUTH SULFIDE Bismuth trioxide Bismuth nitrate pentahydrate Bismuth Triphenylbismuth BISMUTH TITANATE BISMUTH 2-ETHYLHEXANOATE Methanesulfonic acid Trifluoromethane Bismuth(III) trifluoromethanesulfonate

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