Bromomethyl methyl ether

Bromomethyl methyl ether Basic information

Product Name:	Bromomethyl methyl ether
Synonyms:	METHOXYMETHYL BROMIDE;BROMOMETHYL METHYL ETHER;Bromo(methoxy)methane;bromomethoxy-methan;Ether, bromomethyl methyl;Methane, bromomethoxy-;BROMOMETHYL METHYL ETHER, TECH., 90%;BMME~Methoxymethylbromide
CAS:	13057-17-5
MF:	C2H5BrO
MW:	124.96
EINECS:
Product Categories:	Ethers;Organic Building Blocks;Oxygen Compounds
Mol File:	13057-17-5.mol

Bromomethyl methyl ether Chemical Properties

Boiling point	87 °C (lit.)
density	1.531 g/mL at 25 °C (lit.)
refractive index	n20/D 1.456(lit.)
Fp	80 °F
storage temp.	2-8°C
solubility	Chloroform (Soluble), Methanol (Slightly)
form	clear liquid
Specific Gravity	1.531
color	Colorless to Light yellow to Light orange
Water Solubility	Sparingly soluble in water.
Sensitive	Moisture Sensitive
BRN	1730853
CAS DataBase Reference	13057-17-5(CAS DataBase Reference)
NIST Chemistry Reference	Bromomethyl methyl ether(13057-17-5)
EPA Substance Registry System	Methane, bromomethoxy- (13057-17-5)

Safety Information

Hazard Codes	Xn
Risk Statements	10-20/21/22-36/37/38-40
Safety Statements	26-36/37
RIDADR	UN 1992 3/PG 3
WGK Germany	3
TSCA	Yes
HazardClass	6.1
PackingGroup	II
HS Code	29091990

MSDS Information

Provider	Language
SigmaAldrich	English
ALFA	English

Bromomethyl methyl ether Usage And Synthesis

Chemical Properties	Colorless liquid
Uses	Bromomethyl methyl ether is used as reagent for protection of OH groups as their methoxymethyl (MOM) ethers. It is used in enantiocontrolled synthesis of intermediate containing carbons 18 to 35 of the macrocyclic immunosuppressant FK-506. It was used in the synthesis of 1-methoxymethyl-4-tritylthio-2-azetidinone.
Uses	Bromomethyl methyl ether was used in enantiocontrolled synthesis of intermediate containing carbons 18 to 35 of the macrocyclic immunosuppressant FK-506. It was used in the synthesis of 1-methoxymethyl-4-tritylthio-2-azetidinone.

Bromomethyl methyl ether Preparation Products And Raw materials

Raw materials	phenylsulfanol-->Tributyl(methoxymethyl)stannane-->Methanol-->Methyl acetate-->Formaldehyde-->Chloromethyl methyl ether-->Dimethoxymethane-->Acetyl bromide
Preparation Products	1,4-DIMETHOXYBUTANE-->1-(Bromomethyl)naphthalene-->3-methoxy-4-(methoxymethoxy)benzaldehyde-->Benzene, 1-broMo-3-(MethoxyMethoxy)--->1-Fluoro-4-(methoxymethoxy)benzene

(Bromomethyl)cyclopropane Cyclohexylmethyl bromide Pentabromodiphenyl ether Chloromethyl methyl ether tert-Butyl methyl ether Parathion-methyl Tribenuron methyl 4-Bromomethylbenzoic acid Thiophanate-methyl Tetrabromobisphenol A bis(dibromopropyl ether) Pirimiphos-methyl Methyl salicylate Methyl acetate Methyl bromide METSULFURON METHYL Bromotrimethylsilane BROMOPENTAMETHYLBENZENE Bromomethyl methyl ether

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