Chloro(triphenylphosphine)gold

Chloro(triphenylphosphine)gold Basic information
Product Name:Chloro(triphenylphosphine)gold
Synonyms:Chloro(triphenylphosphine)gold(I), 99.9+% metals basis;Chloro(triphenylphosphine)gold(I), 99.9%;CHLORO(TRIPHENYLPHOSPHANE)GOLD(I);Triphenylphosphine aurous chloride;Chlorotriphenylphosphinegold(I),98+%(99.9+%-Au);chloro(triphenylphosphine)gold(i), premion;CHLOROTRIPHENYLPHOSPHINE GOLD(I) , (99.9%-AU);Chlorotriphenylphosphino gold
CAS:14243-64-2
MF:C18H15AuClP
MW:494.71
EINECS:238-117-6
Product Categories:Au;metal-phosphine complexes
Mol File:14243-64-2.mol
Chloro(triphenylphosphine)gold Structure
Chloro(triphenylphosphine)gold Chemical Properties
Melting point 248-249°C
storage temp. Keep in dark place,Inert atmosphere,2-8°C
form Crystalline Powder
color White
Water Solubility Soluble in methylene chloride, acetonitrile, benzene and acetone. Insoluble in water and ethanol.
CAS DataBase Reference14243-64-2(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-22
Safety Statements 26-36/37/39-37/39
RIDADR 3464
WGK Germany 3
HS Code 71159010
MSDS Information
ProviderLanguage
ALFA English
Chloro(triphenylphosphine)gold Usage And Synthesis
Chemical PropertiesWhite crystalline powder
UsesChloro(triphenylphosphine)gold(I) is a common reagent in gold chemistry. It catalyzes certain rearrangement reactions in organic synthesis. It is also used to prepare 1-methylthyminato-N3-triphenylphosphinegold(I) by reacting with 1-methylthymine. It acts as a precursor for the synthesis of gold(I) and gold(III) organometallic compounds.
UsesCatalyst employed in the cyclization of O-propargyl carbamates to alkylideneoxazolidinones via a 5-exo-digonal pathway at room temperature. Also catalyzes the cycloisomerization of enynes containing a cyclic olefin into highly-fused, polycyclic dienes at room temperature.
Chloro(triphenylphosphine)gold Preparation Products And Raw materials
Methylene Chloride Sodium tetrachloroaurate Tris(triphenylphosphine)rhodiu TRIPHENYLPHOSPHINE DIBROMIDE Tetrakis(triphenylphosphine)platinum Calcium chloride Sodium chloride TRIPHENYLPHOSPHINE Difluorochloromethane Black-Gold Choline chloride Ammonium chloride Polyvinyl chloride Triphenylphosphine Potassium chloride Thionyl chloride Bis(triphenylphosphine)palladium(II) chloride 2-​[[(2-​ethylphenyl)​(2-​hydroxyethyl)​amino]​methyl]​-​3,​3-​difluoro-Propanenitrile

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