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9-Fluorenemethanol

9-Fluorenemethanol Basic information
Product Name:9-Fluorenemethanol
Synonyms:TIMTEC-BB SBB008508;AKOS MSC-0133;Fmoc-Oh(9-Fluorenylmethanol);9-Fluorenylmethanol,98+%;9-FLUORENYLMENTHANOL;Fmoc (9-Fluorenemethanol);9-Fluorenemethanol (FMOH);9-FLUOROENYLMETHANOL
CAS:24324-17-2
MF:C14H12O
MW:196.24
EINECS:246-167-5
Product Categories:Fluorenes;Fluorenes & Fluorenones;Amino alcohols;Alkohols;N-Protecting Reagents;Fluorene Derivatives;Peptide coupling agents;Amino Acid Derivatives;Benzocycles;Fluorenes, Flurenones
Mol File:24324-17-2.mol
9-Fluorenemethanol Structure
9-Fluorenemethanol Chemical Properties
Melting point 105-107 °C (lit.)
Boiling point 293.14°C (rough estimate)
density 1.0304 (rough estimate)
refractive index 1.5385 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility Soluble in methanol.
pka13.68±0.10(Predicted)
form Crystalline Powder
color White to pale yellow
BRN 2330017
CAS DataBase Reference24324-17-2(CAS DataBase Reference)
NIST Chemistry ReferenceFluorene-9-methanol(24324-17-2)
EPA Substance Registry System9H-Fluorene-9-methanol (24324-17-2)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 22-24/25-36/37/39-27-26
WGK Germany 3
Hazard Note Irritant
TSCA Yes
HS Code 29062900
MSDS Information
ProviderLanguage
Fluorene-9-methanol English
SigmaAldrich English
ACROS English
ALFA English
9-Fluorenemethanol Usage And Synthesis
Chemical PropertiesWHITE TO PALE YELLOW CRYSTALLINE POWDER
Uses9-Fluorenemethanol, N-protecting reagent, was used in the peptide syntheses. 9-Fluorenemethanol was also used in the synthesis of deoxynucleoside 9-fluorenemethyl phosphorodithioates.
Uses9-Fluorenylmethanol acts as a N-protecting reagent, which is used in the synthesis of peptide. It is also used in the preparation of deoxynucleoside 9-fluorenemethyl phosphorodithioates. Further, it is used to prepare 9-(fluoromethyl)fluorene. In addition to this, it is involved in the electropolymerization with boron trifluoride diethyl etherate to yield low-potential electrodeposition of semiconducting poly(9-fluorenemethanol) film.
General DescriptionVibrational spectroscopy of jet-cooled 9-fluorenemethanol and its clusters 9-fluorenemethanol-H2O, 9-fluorenemethanol-CH3OH, 9-fluorenemethanol-C2H5OH and 9-fluorenemethanol-C3H7OH has been studied by IR-UV double-resonance method. Electropolymerization of 9-fluorenemethanol in boron trifluoride diethyl etherate leads to low-potential electrodeposition of semiconducting poly(9-fluorenemethanol) (PFMO) film.
FMOC-Ala-OH N-alpha-FMOC-Nepsilon-BOC-L-Lysine FMOC-GLN-OH 9-Carboxyfluorene FMOC-L-Methionine Fluorene Fmoc-Cys(tBu)-OH 9-HYDROXYFLUORENE-9-CARBOXYLIC ACID FMOC-PHE-OH 9-FLUORENYLMETHYL PENTAFLUOROPHENYL CARBONATE Hydroxymethyl FMOC-GLU(OTBU)-OH H2O Nalpha-FMOC-L-Tryptophan 9-Fluorenemethanol(Fomc-Oh) FMOC-NLE-OH Nalpha-FMOC-L-Asparagine 9-FLUORENYLMETHANOL, [9-FLUORENEMETHANOL; 9-(HYDROXY-METHYL)FLUORENE] 9-Fluorenemethanol
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