(E)-4-Hexen-1-ol

(E)-4-Hexen-1-ol Basic information

Product Name:	(E)-4-Hexen-1-ol
Synonyms:	FEMA 3430;4-Hexen-1-ol,predominantly trans;4-Hexen-1-ol ,97%;(4E)-4-Hexene-1-ol;4-Hexen-1-ol, (4E)-;4-Hexen-1-ol, (E)-;Ai3-34796;Einecs 213-188-6
CAS:	928-92-7
MF:	C6H12O
MW:	100.16
EINECS:	213-188-6
Product Categories:	Alcohol& Phenol& Ethers;Acyclic;Alkenes;Organic Building Blocks;Organic Building Blocks
Mol File:	928-92-7.mol

(E)-4-Hexen-1-ol Chemical Properties

Melting point	22.55°C (estimate)
Boiling point	159-160 °C(lit.)
density	0.851 g/mL at 25 °C(lit.)
FEMA	3430 \| 4-HEXEN-1-OL
refractive index	n20/D 1.439(lit.)
Fp	142 °F
storage temp.	Refrigerator, under inert atmosphere
solubility	Chloroform, Methanol (Slightly)
form	Liquid
pka	15.13±0.10(Predicted)
color	Colorless
Odor	at 10.00 % in dipropylene glycol. green herbal musty tomato metallic
Odor Type	green
Water Solubility	Slightly soluble in water.
JECFA Number	318
LogP	1.285 (est)
CAS DataBase Reference	928-92-7(CAS DataBase Reference)
NIST Chemistry Reference	4-Hexen-1-ol, (E)-(928-92-7)
EPA Substance Registry System	(E)-4-Hexen-1-ol (928-92-7)

Safety Information

Hazard Codes	Xi
Risk Statements	36
Safety Statements	26
RIDADR	1993
WGK Germany	3
TSCA	Yes
HazardClass	3.2
PackingGroup	III
HS Code	29061990

MSDS Information

Provider	Language
(E)-4-Hexen-1-ol	English
SigmaAldrich	English

(E)-4-Hexen-1-ol Usage And Synthesis

Chemical Properties	Colorless liquid
Uses	4-Hexen-1-ol has been employed in the preparation of hex-4-enals.
Uses	4-Hexen-1-ol on reaction with NaIO4/NaHSO3?reagent yields 2-(1-iodoethyl)tetrahydrofuran. has been employed in the preparation of hex-4-enals.
Definition	ChEBI: 4-Hexen-1-ol, (E)- is an aliphatic alcohol.
Synthesis Reference(s)	Synthetic Communications, 21, p. 435, 1991 DOI: 10.1080/00397919108016767
General Description	4-Hexen-1-ol on reaction with NaIO₄/NaHSO₃ reagent yields 2-(1-iodoethyl)tetrahydrofuran.

(E)-4-Hexen-1-ol Preparation Products And Raw materials

Raw materials	(Trans)ethyl 4-hexenoate-->(E)-4-Hexenoic acid-->4-Hexenoic acid ethyl ester-->TRANS-3-HEXEN-1-OL-->HEXENAL-->TRANS,TRANS-2,4-HEXADIEN-1-OL-->5,6-Dihydro-2-methyl-2H-pyran-->hex-4-yn-1-ol-->5-Hexen-1-ol
Preparation Products	3-METHYL-4-PENTEN-1-OL-->4-Hexen-1-ol, 1-acetate-->(Z)-Hex-4-en-1-ol-->Leaf alcohol-->2-Hexene, 6-methoxy-, (2E)-

6-METHYL-5-HEPTEN-2-OL ACETIC ACID LAVANDULYL ESTER RUBRATOXIN B CYMARIN CYTOCHALASIN E APOCHOLIC ACID (2R,3R,4S)-2-(tert-Butyldimethylsilyloxy)-4-methyl-5-hexen-3-ol 20(22),5BETA-CARDENOLID-3BETA,14BETA,16BETA-TRIOL 3,16-DIACETATE trans,trans-2,4-Undecadienal DIETHYL 1,4-DIHYDRO-2,4,6-TRIMETHYL-3,5-PYRIDINEDICARBOXYLATE (+/-)-LAVANDULOL 4-Hexen-l-ol DIGITOXIGENIN TRANS,TRANS-2,4-HEXADIEN-1-OL (2S,3S)-2-(Benzyloxy)-5-hexen-3-ol HEMATOPORPHYRIN 3,4-DIHYDRO-2,2-DIMETHYL-4-OXO-2H-PYRAN-6-CARBOXYLIC ACID (E)-4-Hexen-1-ol

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