ChemicalBook Product Catalog Chemical Reagents Organic reagents Esters Carboxylic Acid Esters tert-Butyl phenyl carbonate

tert-Butyl phenyl carbonate

tert-Butyl phenyl carbonate Basic information
Product Name:tert-Butyl phenyl carbonate
Synonyms:(2-tert-butylphenyl) carbonate;(tert-Butoxycarbonyloxy)benzene;Carbonic acid O-phenyl O-tert-butyl ester;Carbonic acid O-tert-butyl O-phenyl ester;Carbonic acid tert-butylphenyl ester;Einecs 229-601-8;Carbonicacidtert-butylesterphenylester;ert-Butyl phenyl carbonate
CAS:6627-89-0
MF:C11H14O3
MW:194.23
EINECS:229-601-8
Product Categories:Organic Building Blocks;Carbonates;Carbonyl Compounds
Mol File:6627-89-0.mol
tert-Butyl phenyl carbonate Structure
tert-Butyl phenyl carbonate Chemical Properties
Boiling point 83 °C/0.6 mmHg (lit.)
density 1.05 g/mL at 20 °C (lit.)
refractive index n20/D 1.480
Fp 214 °F
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform (Slightly)
form Liquid or Low Melting Solid
color Colorless
Water Solubility Slightly soluble in water.
BRN 2361602
NIST Chemistry ReferenceCarbonic acid 1,1-dimethylethyl ester(6627-89-0)
Safety Information
Safety Statements 23-24/25
WGK Germany 3
F 21
HS Code 29209090
MSDS Information
ProviderLanguage
SigmaAldrich English
tert-Butyl phenyl carbonate Usage And Synthesis
Chemical PropertiesClear light yellow liquid
Usestert-Butyl phenyl carbonate is used in determination of octanol-water partition coefficients by microemulsion electrokinetic chromatography. It is also used in the synthesis of 2-nitroindoles and as a reagent for mono-Boc protection of α,ω-diamines.
Purification MethodsIf IR is free from OH, then purify it by redistillation; otherwise dissolve it in Et2O, wash it with 5% HCl, then H2O, dry it (MgSO4), evaporate and distil it through a Claisen head under vacuum. Care should be taken as distillation of large quantities can lead to decomposition with liberation of CO2 and isobutylene; use the necessary precautions. [Carpino J Am Chem Soc 79 98 1957, Beilstein 6 IV 629.]
tert-Butyl phenyl carbonate Preparation Products And Raw materials
Preparation ProductsN-BOC-1,6-diaminohexane-->tert-Butyl N-(4-aminobutyl)carbamate-->1,9-BIS-BOC-1,5,9-TRIAZANONANE-->1-PHENYLPYRROLE-->N-Boc-cadaverine
P-O-T-BOC-BENZYLMETHANETHIOSULFONATE 3-O-METHYL-4-O-BOC-6-TRIMETHYLSTANNYL-L-DOPA T -BUTYL-P-NITROPHENYL CARBONATE TERT-BUTYL PENTACHLOROPHENYL CARBONATE 2-TT CARBONIC ACID TERT-BUTYL 2,4,5-TRICHLOROPHENYL ESTER BOC-TYR(BOC)-OH (ALPHA,ALPHA-DIMETHYL-3,5-DIMETHOXYBENZYL)-4-NITROPHENYLCARBONATE BPOC REAGENT TERT-BUTYL-3-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENYL CARBONATE 3-(TERT-BUTOXYCARBONYL)PHENYLBORONIC ACID DIBOC-6-TRIMETHYLSTANNYL-L-PHENYLALANINE ETHYL ESTER P-O-T-BOC-BENZYL ALCOHOL L-TYROSINE, 5-[[(1,1-DIMETHYLETHOXY)CARBONYL]OXY]-N-[(1,1-DIMETHYLETHOXY)CARBONYL]-2-(TRIMETHYLSTANNYL)-, METHYL ESTER, 1,1-DIMETHYLETHYL CARBONATE TERT-BUTYL 4-FORMYLPHENYL CARBONATE tert-butyl 8-quinolyl carbonate Tert-Butyl 4-Vinylphenyl Carbonate tert-Butyl phenyl carbonate
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