BENZYL PHENYL ETHER

BENZYL PHENYL ETHER Basic information

Product Name:	BENZYL PHENYL ETHER
Synonyms:	(Phenoxymethyl)-benzene;alpha-Phenylanisole;Anisole, alpha-phenyl-;Ether, benzyl phenyl;PHENYL BENZYL ETHER;TIMTEC-BB SBB008247;BENZYL PHENYL ETHER;BENZYLOXY-BENZENE
CAS:	946-80-5
MF:	C13H12O
MW:	184.23
EINECS:
Product Categories:	Ethers;Organic Building Blocks;Oxygen Compounds
Mol File:	946-80-5.mol

BENZYL PHENYL ETHER Chemical Properties

Melting point	39-41 °C (lit.)
Boiling point	286-287 °C (lit.)
density	1.0120 (rough estimate)
refractive index	1.5641 (estimate)
Fp	>230 °F
storage temp.	Inert atmosphere,2-8°C
form	Chunks
color	Light brown-orange
Water Solubility	Insoluble in water.
BRN	2045713
CAS DataBase Reference	946-80-5(CAS DataBase Reference)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36
WGK Germany	3
HS Code	29093090

MSDS Information

Provider	Language
SigmaAldrich	English
ALFA	English

BENZYL PHENYL ETHER Usage And Synthesis

Chemical Properties	Light brown-orange chunks
Uses	Benzyl phenyl ether reacts with aluminum bromide in chlorobenzene solution to afford a mixture of phenol, o-benzyl phenol and dichlorodiphenylmethane. It is a useful as model compound in catalytic chemistry to represent the a-O4 ether bond in lignin and coal. It contains a weak ether bond of 234kJ/mol and belongs to the most thermo-labile compounds in lignin and low rank coal. Influence of alkali carbonates, common additives in biomass conversion, on the reaction pathways of BPE in superheated water has been reported. Cesium-exchanged heteropolyacid catalyzed decomposition of benzyl phenyl ether to aromatics has been investigated. Photo-Claisen rearrangements of benzyl phenyl ether was investigated in cation-exchanged Y zeolites and polyethylenes of differing crystallinities.
General Description	Benzyl phenyl ether is a reactive organic oxygenate, containing ether as functional group, present in subbituminous and bituminous coals. It reacts with aluminium bromide in chlorobenzene solution to afford a mixture of phenol, o-benzyl phenol and dichlorodiphenylmethane. It is a useful as model compound in catalytic chemistry to represent the a-O4 ether bond in lignin and coal. It contains a weak ether bond of 234kJ/mol and belongs to the most thermo-labile compounds in lignin and low rank coal. Influence of alkali carbonates, common additives in biomass conversion, on the reaction pathways of BPE in superheated water has been reported. Cesium-exchanged heteropolyacid catalyzed decomposition of benzyl phenyl ether to aromatics has been investigated. Photo-Claisen rearrangements of benzyl phenyl ether was investigated in cation-exchanged Y zeolites and polyethylenes of differing crystallinities.

BENZYL PHENYL ETHER Preparation Products And Raw materials

Raw materials	1-(benzyloxy)-1H-1,2,3-benzotriazole-->4-BENZYLOXYCHLOROBENZENE-->4-Benzyloxybromobenzene-->3-FLUOROBENZYLOXYBENZENE-->4-BENZYLOXYIODOBENZENE-->2-Benzyloxybenzaldehyde-->3-BENZYLOXYBROMOBENZENE-->BENZYL 4-TOLUENESULFONATE-->Monobenzone-->Phenylboronic acid-->Phenol
Preparation Products	6H-Dibenzo[b,d]pyran-->4-BENZYLPHENOL-->2-Hydroxydiphenylmethane

3,5-Dibenzyloxyacetophenone 3-BENZYLOXYBENZYL ALCOHOL 4-CYANOPHENYL 4-N-BUTYLBENZOATE PHENYL 3-HYDROXY-2-NAPHTHOATE 4-[4-(3,4-dihydro-2(1H)-isoquinolinylcarbonyl)-2-quinolinyl]benzyl phenyl ether 4-(Benzyloxy)benzyl chloride H-TYR(BZL)-OH 4-BENZYLOXY-3-METHOXYBENZALDEHYDE 4-CYANOPHENYL 4-HEPTYLBENZOATE 3,4-Dibenzyloxybenzaldehyde 3-(1,3-benzothiazol-2-yl)benzyl phenyl ether fomocaine (4-(1-methyl-3-(morpholin-4-yl)propyl)benzyl)-phenyl-ether [4-[1-Methyl-3-(morpholine-4-yl)propyl]benzyl]phenyl ether fomocaine (4-(2-methyl-3-(morpholin-4-yl)propyl)benzyl)-phenyl-ether Phenyl benzoate 4-BENZYLOXY-3-METHOXYBENZYL ALCOHOL Estradiol benzoate 1-benzyl-2-(3-bromopropoxy)benzene

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