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4-THIOANISOLEMAGNESIUM BROMIDE

4-THIOANISOLEMAGNESIUM BROMIDE Basic information
Product Name:4-THIOANISOLEMAGNESIUM BROMIDE
Synonyms:4-THIOANISOLEMAGNESIUM BROMIDE, 0.5M SOLUT TION IN TETRAHYDROFURAN;4-THIOANISOLEMAGNESIUM BROMIDE;4-thioanisolemagnesium bromide solution;4-Thioanisolemagnesium bromide, 0.5M solution in THF, AcroSeal;4-Thioanisolemagnesium bromide,0.5M solutionin THF;4-ThioanisoleMagnesiuM broMide, 0.5 M solution in THF, J&KSeal;4-(Methylthio)phenylmagnesium bromide;magnesium,methylsulfanylbenzene,bromide
CAS:18620-04-7
MF:C7H7BrMgS
MW:227.4
EINECS:
Product Categories:Chemical Synthesis;Grignard Reagents;Aryl;Grignard Reagents;Organometallic Reagents;Organometallic Reagents
Mol File:18620-04-7.mol
4-THIOANISOLEMAGNESIUM BROMIDE Structure
4-THIOANISOLEMAGNESIUM BROMIDE Chemical Properties
Boiling point 65 °C
density 0.965 g/mL at 25 °C
Fp <1 °F
storage temp. 2-8°C
form Solution
color Clear yellow to brown
Safety Information
Hazard Codes F,C,F+
Risk Statements 11-14-19-34-12-37-40
Safety Statements 16-26-36/37/39-45
RIDADR UN 2924 3/PG 2
WGK Germany 1
HS Code 29309090
MSDS Information
ProviderLanguage
SigmaAldrich English
4-THIOANISOLEMAGNESIUM BROMIDE Usage And Synthesis
Chemical PropertiesTan liquid
Uses4-Thioanisolemagnesium bromide can be used to prepare:
  • 3,3-Ethylenedioxy-5a-hydroxy-11b-[4-(thiomethoxy)phenyl]-estr-9-en-17-one, a key intermediate for the synthesis of mifepristone analogs.
  • (1S)-1,4-Anhydro-2,3,5,6-tetra-O-benzyl-1-C-[4-chloro-3-(4-methylthiobenzyl)-phenyl]-D-glucitol, a key intermediate for the synthesis of aryl?D-glucofuranosides as potent hSGLT2 and hSGLT1 inhibitors.

4-THIOANISOLEMAGNESIUM BROMIDE Preparation Products And Raw materials
4-TERT-BUTYLPHENYLMAGNESIUM BROMIDE 4-Fluorophenylmagnesium chloride 4-METHYLBENZYLMAGNESIUM CHLORIDE 4-Methoxyphenylmagnesium bromide P-TOLYLMAGNESIUM CHLORIDE (TRIMETHYLSILYL)METHYLLITHIUM 3-(DIMETHYLAMINO)PROPYL CHLORIDE HYDROCHLORIDE Tricyclohexyl phosphine (TRIMETHYLSILYL)DIAZOMETHANE 4-ETHYLPHENYLMAGNESIUM BROMIDE Chloromethane DIMETHYLALUMINUM CHLORIDE 2-METHOXYPHENYLMAGNESIUM BROMIDE PHENYLMAGNESIUM BROMIDE 4-(ETHYLTHIO)PHENYLMAGNESIUM BROMIDE Methylmagnesium Bromide 2-THIOANISOLEMAGNESIUM BROMIDE 4-THIOANISOLEMAGNESIUM BROMIDE
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