2-Bromo-4-methylbenzaldehyde

2-Bromo-4-methylbenzaldehyde Basic information
Product Name:2-Bromo-4-methylbenzaldehyde
Synonyms:2-BROMO-P-TOLUALDEHYDE;2-BROMO-4-METHYLBENZALDEHYDE;2-Bromo-4-methylbenzaldehyde,2-bromo-p-tolualdehyde;2-Bromo-4-methylbenzaldehyde ,98%;2-BROMO-4-2-Bromo-4-methylbenzaldehyde;2-Bromo-p-tolualdehyde, 3-Bromo-4-formyltoluene;2-Bromo-4-methylbenzaldehyde technical grade;Benzaldehyde, 2-bromo-4-methyl-
CAS:824-54-4
MF:C8H7BrO
MW:199.04
EINECS:625-357-5
Product Categories:Aldehydes;Building Blocks;C8;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks
Mol File:824-54-4.mol
2-Bromo-4-methylbenzaldehyde Structure
2-Bromo-4-methylbenzaldehyde Chemical Properties
Melting point 30-35 °C (lit.)
Boiling point 114-115 °C(Press: 5 Torr)
density 1.490±0.06 g/cm3(Predicted)
Fp >230 °F
storage temp. Keep in dark place,Inert atmosphere,Room temperature
form powder
color Yellow
Sensitive Air Sensitive
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 29124990
MSDS Information
ProviderLanguage
SigmaAldrich English
2-Bromo-4-methylbenzaldehyde Usage And Synthesis
Chemical PropertiesWhite to yellow solid
UsesReactant involved in:
  • Carbonylative Stille couplings followed by isomerization and intramolecular Heck reactions
  • Knoevenagel condensation
  • Cyclization of N-(α-methyl-p-methoxybenzyl)-imino-esters
  • Imination and oxidative heterocyclization / carbonylation
  • Intramolecular amination
  • Intermolecular and intramolecular hydroacylation of alkenes by aromatic aldehydes
UsesReactant involved in:• ;Carbonylative Stille couplings followed by isomerization and intramolecular Heck reactions1• ;Knoevenagel condensation2• ;Cyclization of N-(α-methyl-p-methoxybenzyl)-imino-esters3• ;Imination and oxidative heterocyclization / carbonylation4• ;Intramolecular amination5• ;Intermolecular and intramolecular hydroacylation of alkenes by aromatic aldehydes6
Uses2-Bromo-4-methylbenzaldehyde is a useful intermediate for organic synthesis.
2-Bromo-4-methylbenzoic acid 3-BROMO-4-METHYLBENZALDEHYDE TOLUALDEHYDES 3-(Trifluoromethyl)benzaldehyde p-Tolualdehyde 3-Bromoanisole 4-Dimethylaminobenzaldehyde 5-BROMO-2-METHYLBENZALDEHYDE 3-BROMO-4-METHYLBENZALDEHYDE DIMETHYL ACETAL 2-bromo-5-methylbenzaldehyde 4-(Trifluoromethyl)benzaldehyde Benzyl bromide Bromine Cyclohexylmethyl bromide 2-Bromo-4-methylbenzaldehyde Bromotrimethylsilane BROMOPENTAMETHYLBENZENE

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