ChemicalBook Product Catalog Biochemical Engineering Amino Acids and proteins D-2-Phenylglycine

D-2-Phenylglycine

D-2-Phenylglycine Basic information
Description Storage
Product Name:D-2-Phenylglycine
Synonyms:.alpha.-amino-,(R)-Benzeneaceticacid;Benzeneacetic acid, alpha-amino-, (R)-;Benzeneaceticacid,alpha-amino-,(R)-;D-(-)-2-Phenylglycine,99%;(R)-(-)-ALPHA-AMINOPHENYLACETIC ACID FOR RESOLUTION OF RACEMATES;D(-)-alpha-Aminophenylacetic;D-a-a(1,4-cyclohexadienyl)Glyc;Benzeneacetic acid, .alpha.-amino-, (.alpha.R)-
CAS:875-74-1
MF:C8H9NO2
MW:151.16
EINECS:212-876-3
Product Categories:pharmaceutical;Antidote / Antibiotic / Antimicrobial;GLYCINESCAFFOLD;Phenylglycine [Phg];Unusual Amino Acids;Amino Acids;Pharmaceutical Intermediates;Amino ACIDS SERIES
Mol File:875-74-1.mol
D-2-Phenylglycine Structure
D-2-Phenylglycine Chemical Properties
Melting point 302 °C (dec.)(lit.)
alpha -156 º (c=1,1N HCl)
Boiling point 273.17°C (rough estimate)
density 1.2 g/cm3 (20℃)
vapor pressure 0Pa at 25℃
refractive index -158 ° (C=1, 1mol/L HCl)
Fp 150 °C
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Aqueous Acid (Sparingly), Water (Slightly, Heated)
pka1.94±0.10(Predicted)
form Crystalline Powder
color White
optical activity[α]20/D 155°, c = 1 in 1 M HCl
Water Solubility 0.3g/100mL
Merck 14,7291
BRN 2208676
LogP-1.76 at 20℃
CAS DataBase Reference875-74-1(CAS DataBase Reference)
NIST Chemistry Referenced a-Phenylglycine(875-74-1)
EPA Substance Registry SystemBenzeneacetic acid, .alpha.-amino-, (.alpha.R)- (875-74-1)
Safety Information
Hazard Codes T
Risk Statements 23/24/25-36/37/38-22-20
Safety Statements 22-24/25-45-36/37/39-26-44-28-7-4
WGK Germany 3
TSCA Yes
HS Code 29224995
MSDS Information
ProviderLanguage
D(-)-alpha-Phenylglycine English
ACROS English
SigmaAldrich English
ALFA English
D-2-Phenylglycine Usage And Synthesis
DescriptionL-phenylglycine (Cephalexin EP Impurity A) is a derivative of glycine, a non-essential amino acid for human development. Glycine is an inhibitory neurotransmitter in the spinal cord and an allosteric modulator of NMDA receptors.
StorageStore at room temperature. Store in cool dry place in tightly closed container. Store away from oxidizing agent.
Chemical PropertiesWhite crystalline powder
UsesD-(-)-2-Phenylglycine is the derivative of glycine (G615990), a non-essential amino acid for human development. Glycine is an inhibitory neurotransmitter in spinal cord, allosteric regulator of NMDA r eceptors.
UsesD-(-)-2-Phenylglycine (Cefalexin EP Impurity A) is the derivative of glycine (G615990), a non-essential amino acid for human development. Glycine is an inhibitory neurotransmitter in spinal cord, allosteric regulator of NMDA receptors.
DefinitionChEBI: The R stereoisomer of alpha-phenylglycine.
Flammability and ExplosibilityNonflammable
D-2-Phenylglycine Preparation Products And Raw materials
Preparation ProductsAmpicillin-->(2R)-2-[(4-Ethyl-2,3-dioxopiperazinyl)carbonylamino]-2-phenylacetic acid-->1R，3R-chrysanthemic acid-->(R)-(-)-2-Phenylglycine chloride hydrochloride-->Potassium (R)-[(3-ethoxy-1-methyl-3-oxoprop-1-enyl)amino]phenylacetate-->FMOC-D-PHG-OH-->Benzeneacetic acid, α-(diethylamino)-, (αR)--->Benzeneacetic acid, α-[(1-methylethyl)amino]-, (R)- (9CI)
Potassium (R)-((3-ethoxy-1-methyl-3-oxoprop-1-enyl)amino)(4-hydroxyphenyl)acetate L-Phenylethylamine Ethyl 2-(Chlorosulfonyl)acetate (S)-Amlodipine Ascoric Acid A,A-DIPHENYL-4-MORPHOLINEACETIC ACID, SODIUM SALT Folic acid α-Lipoic Acid Glycine 4-Aminophenylacetic acid BOC-D-PHG-OH Anilinoacetic acid 2,2-Diphenylglycine 4-Hydroxy-D-(-)-2-phenylglycine L-PHENYLGLYCINE METHYL ESTER HYDROCHLORIDE,L-PHENYLGLYCINE METHYL ESTER HCL,L-PHENYLGLYCINE METHYL ESTER HYDROCHLORIDE SALT D-2-Phenylglycine Diethylstilbestrol Citric acid
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