SELENO-DL-METHIONINE

SELENO-DL-METHIONINE Basic information
Product Name:SELENO-DL-METHIONINE
Synonyms:2-AMINO-4-(METHYLSELENO)BUTYRIC ACID;AURORA KA-6143;D,L-2-AMINO-4-(METHYLSELENO)BUTANOIC ACID;DL-SELENOMETHIOININE;DL-SELENOMETHIONINE-13C1 (METHYL-13C) 99;D L-SELENOMETHIONINE 99+%;(+-)-butanoicaci;rac-(2R*)-2-[2-(Methylseleno)ethyl]glycine
CAS:2578-28-1
MF:C5H11NO2Se
MW:196.11
EINECS:678-482-2
Product Categories:Biochemistry;Biological-modified Amino Acids;Classes of Metal Compounds;Se (Selenium) Compounds;Semimetal Compounds;Amino Acids
Mol File:2578-28-1.mol
SELENO-DL-METHIONINE Structure
SELENO-DL-METHIONINE Chemical Properties
Melting point 267-269 °C
storage temp. −20°C
solubility 0.5 M HCl: 50 mg/mL, clear, colorless
form Glistening Powder
color Colorless
Merck 8441
CAS DataBase Reference2578-28-1(CAS DataBase Reference)
Safety Information
Hazard Codes T,N
Risk Statements 23/25-33-50/53
Safety Statements 20/21-28-45-60-61-28A
RIDADR UN 3283 6.1/PG 2
WGK Germany 3
RTECS ES7110000
10
HazardClass 6.1(a)
PackingGroup II
HS Code 29319090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
SELENO-DL-METHIONINE Usage And Synthesis
Chemical Propertiescolorless, faint smelling, glistening powder
DefinitionChEBI: Selenomethionine is a selenoamino acid that is the selenium analogue of methionine. It has a role as a plant metabolite. It is a member of selenomethionines and a selenoamino acid.
HazardA poison.
Purification MethodsIt crystallises in hexagonal plates from MeOH and H2O. [Klosterman & Painter J Am Chem Soc 69 2009 1949.] The L-isomer [3211-76-5] is purified by dissolving it in H2O, adjusting the pH to 5.5 with aqueous NH3, evaporating to near-dryness, and the residue is washed several times with absolute EtOH till a solid is formed and then recrystallise from Me2CO. It has m 266-268o(dec) [also 275o(dec)], and [] D +18.1o(c 1, N HCl). [Pande et al. J Org Chem 35 1440 1970, Beilstein 4 IV 3216.]
SELENO-DL-METHIONINE Preparation Products And Raw materials
Raw materialsselenohomocystine-->ALPHA-AMINO-GAMMA-BUTYROLACTONE HYDROBROMIDE-->2(3H)-Furanone,3-aminodihydro-(8CI,9CI)-->Dimethyldiselenide
Preparation ProductsPIPERAZINE-2,3-DIONE
Ascorbic Acid DL-Selenomethionine L-Selenomethionine L-Methionine

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