ChemicalBook Product Catalog Chemical Reagents Desulfurizer TRIFLUOROMETHANESULFONIMIDE

TRIFLUOROMETHANESULFONIMIDE

TRIFLUOROMETHANESULFONIMIDE Basic information
Product Name:TRIFLUOROMETHANESULFONIMIDE
Synonyms:TRIFLUOROMETHANESULFONIMIDE;Bis(trifluoromethanesulfonyl)amine, Bis(trifluoromethylsulfonyl)amine;Bis(trifluoromethane)sulfonimide,Bis(trifluoromethanesulfonyl)amine, Bis(trifluoromethylsulfonyl)amine;Trifluoromethanesulfonimide,Bis(trifluoromethanesulfonyl)amine;Trifluoromethansulfonimide;BISTRIFLUOROMETHANESULFONIMIDE SOL., ~0. 5 M IN DICHLOROM.;N,N-Bis(trifluoromethylsulfonyl)amine;bis(trifluoromethane)sulfonimide solution
CAS:82113-65-3
MF:C2HF6NO4S2
MW:281.15
EINECS:435-300-4
Product Categories:Trifluoromethylation;Chemical Synthesis;Fluorination;Fluorination Reagents;Synthetic Reagents;Building Blocks;Organic Building Blocks;Sulfonimides/Sulfinimides;Sulfur Compounds
Mol File:82113-65-3.mol
TRIFLUOROMETHANESULFONIMIDE Structure
TRIFLUOROMETHANESULFONIMIDE Chemical Properties
Melting point 52-56 °C
Boiling point 90-91 °C(lit.)
density 1.36
storage temp. 2-8°C
solubility 800g/l Risk of violent reaction.
form Crystals
pka-10.42±0.40(Predicted)
color Colorless to brownish
PH0.8 (100g/l, H2O, 20℃)Risk of violent reaction.
BRN 4754101
Stability:Stable. Incompatible with strong oxidizing agents. Reacts violently with water.
InChIKeyZXMGHDIOOHOAAE-UHFFFAOYSA-N
LogP-0.771 at 25.5℃ and pH6.7
CAS DataBase Reference82113-65-3(CAS DataBase Reference)
EPA Substance Registry SystemMethanesulfonamide, 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]- (82113-65-3)
Safety Information
Hazard Codes C
Risk Statements 34-40-14-67-37
Safety Statements 26-36/37/39-45-8
RIDADR UN 3265 8/PG 2
WGK Germany 3
F 3-10-21
Hazard Note Corrosive
HazardClass 8
PackingGroup I
HS Code 29350090
MSDS Information
ProviderLanguage
SigmaAldrich English
TRIFLUOROMETHANESULFONIMIDE Usage And Synthesis
Chemical Propertieslight yellow to brown liquid
UsesTrifluoromethanesulfonimide may be used as a catalyst for the preparation of 1-substituted-1H-1,2,3,4-tetrazoles.
Uses1,1,1-Trifluoro-N-((trifluoromethyl)sulfonyl)methanesulfonamide is commonly used as a strong acid to prepare Lewis Acid catalysts. It can also be used to improve efficiency of graphene/silicon Schottky solar cells by chemical doping and as a solvent for recycling battery electrodes.
UsesTrifluoromethanesulfonimide is a strong acid, used in the preparation of highly efficient Lewis acid catalysts.
General DescriptionBis(trifluoromethane)sulfonimide (TFSI, Tf2N) is utilized as anion species to form 1-ethyl-3-methylimidazolium molten salts. It undergoes acid-base complexation with rod-like poly(2,5-pyridine) to afford highly-ordered lamellar self-assemblies in the hydrated films.
TRIFLUOROMETHANESULFONIMIDE Preparation Products And Raw materials
Preparation Products1-BUTYL-1-METHYLPYRROLIDINIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE-->Sliver bis(trifluoromethane sulfonimide)-->1-IODO-3,4-METHYLENEDIOXYBENZENE
Bis(4-biphenylyl)amine CYCLOHEXYLTRIMETHYLAMMONIUM BIS(TRIFLUOROMETHANESULFONYL)IMIDE METHYL-TRIOCTYLAMMONIUM BIS(TRIFLUOROMET 1 2-DIME-3-PROPYLIMIDAZOLIUM BIS(TRIFLUO N-(2-PYRIDYL)BIS(TRIFLUOROMETHANESULFONIMIDE) BISTRIFLUOROMETHANESULFONIMIDE TETRAETHYLAMMONIUM SALT TETRABUTYLAMMONIUM BIS-TRIFLUOROMETHANE& YTTERBIUM(III)TRIFLUOROMETHANESULFONIMIDE N,N-DIETHYL-N-METHYL-N-(2-METHOXYETHYL)AMMONIUM BIS(TRIFLUOROMETHANE SULUFONYL)IMIDE SCANDIUM TRIFLUOROMETHANESULFONIMIDE,Scandium(III) trifluoromethanesulfonimide N-PROPYL-3-METHYLPYRIDINIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE, 99% [PMPIM] SILVER BIS(TRIFLUOROMETHANESULFONYL)IMIDE 1-BUTYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOR Magnesium trifluoromethanesulfonimide hydrate MAGNESIUM TRIFLUOROMETHANESULFONIMIDE TRIHEXYL(TETRADECYL)PHOSPHONIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE TRIFLUOROMETHANESULFONIMIDE 1-BUTYL-3-METHYLPYRIDINIUM BIS(TRIFLUORM
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