TRIAZAMATE

TRIAZAMATE Basic information
Product Name:TRIAZAMATE
Synonyms:TRIAZAMATE;APHISTAR;Ethyl (1-dimethylaminocarbonyl-3-(1,1-dimethylethyl)-1H-1,2,4-triazol-5-ylthio)acetate;Ethyl (3-tert-butyl-1-dimethylcarbamoyl-1H-1,2,4-triazol-5-ylthio)acetate;triazamate (bsi,pa e-iso);Acetic acid, ((1-((dimethylamino)carbonyl)-3-(1,1-dimethylethyl)-1H-1,2,4-triazol-5-yl)thio)-, ethyl ester;Acetic acid, ((1-[(dimethylamino)carbonyl]-3-(1,1-dimethylethyl)-1H-1,2,4-triazol-5-yl)thio)-, ethyl ester;Triazamate [iso:bsi]
CAS:112143-82-5
MF:C13H22N4O3S
MW:314.4
EINECS:
Product Categories:INSECTICIDE
Mol File:112143-82-5.mol
TRIAZAMATE Structure
TRIAZAMATE Chemical Properties
Melting point 60°
Boiling point 280°C (rough estimate)
density 1.2357 (rough estimate)
vapor pressure 1.6 x l0-4 Pa (25 °C)
refractive index 1.6200 (estimate)
Fp 189℃
form neat
pka0.48±0.50(Predicted)
Water Solubility 433 mg l-1(25 °C)
BRN 8422595
EPA Substance Registry SystemTriazamate (112143-82-5)
Safety Information
Hazard Codes T,N
Risk Statements 23-25-36-50
Safety Statements 26-45-61
RIDADR UN2811 - class 6.1 - PG 2 - EHS - Toxic solids, organic, n.o.s., HI: all
WGK Germany 3
ToxicityLD50 (14 d) in mice, rats (mg/kg): 61, 50-200 orally; in rats (mg/kg): >5000 dermally (Murray); LC50 (48 h) in daphnia: 0.048 mg/l; (96 h) in bluegill, trout: 1.0, 0.43 mg/l (Murray)
MSDS Information
TRIAZAMATE Usage And Synthesis
UsesPesticide.
UsesTriazamate is used for the control of aphids by foliar application on a wide variety of crops. It is suitable for inclusion in integrated pest management because it is minimally toxic to beneficial insects.
UsesTriazamate is used in controlling unpleasant pests.Used in preparation of Thiazole Manganese Zinc compounds and compounds thereof.
DefinitionChEBI: A triazole insecticide that is 1H-1,2,4-triazole which is substituted at positions 1, 3, and 5 by N,N-dimethylaminocarbonyl, tert-butyl, and (2-ethoxy-2-oxoethyl)sulfanediyl groups, resp ctively.
General DescriptionTriazamate is a carbamoyl triazole compound, widely used as an insecticide and its mode of action involves the inhibition of cholinesterase in insect pests.
Metabolic pathwayThere is only a limited amount of information on the fate of triazamate currently in the public domain. Metabolism in sugar beet and apple has been reported. Animal metabolism studies have been conducted but details are not available. Triazamate is very rapidly metabolised by hydrolysis, decarbamoylation and further metabolism in all biological systems studied (PM).
DegradationTriazamate is stable under normal conditions and in solution at pH 7 and below. Its DT50 values in buffers are, at pH 5, 7 and 9, 220 days, 49 hours and 1 hour, respectively (PM). Base-catalysed hydrolysis should initially afford triazamate acid (2) by carboxyl ester cleavage (see Scheme 1).
The DTM of triazamate on aqueous photolysis at pH 7 is 301 days (PM)
TRIAZAMATE Preparation Products And Raw materials
Cyenopyrafen Zoledronic acid 5-ethyl-6-octyl-[1,2,3]triazolo[1,5-a]pyriMidin-7-aMine Fenpyroximate [4-chloro-2-(hydroxymethyl)phenoxy]acetic acid Fenbendazole Ethyl chloroacetate 3-tert-butyl-1H-1,2,4-triazole-5-thiol CHEMBRDG-BB 7433700 1-(Dimethylcarbamoyl)-3-tert-butyl-5-(methylthio)-1H-1,2,4-triazole 5-ISOPROPYL-4H-[1,2,4]TRIAZOLE-3-THIOL TRIAZAMATE

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