(R)-(-)-Epichlorohydrin

(R)-(-)-Epichlorohydrin Basic information
Product Name:(R)-(-)-Epichlorohydrin
Synonyms:(R)-3-Chloro-1,2-epoxypropane;2-(Chlorometyl)oxirane;R(-)-2-(CHLOROMETHYL)OXIRANE;(R) Epichlorohydin or (R)1-chloro-2,3-epoxypropane;(R)-(-)-Epichlorohydrin,99%;2-(Chloromethyl)oxirane;(R)-()-Epichlorohydrin,(R)-()-2-(Chloromethyl)oxirane;(R)-(-)-Epichlorohyd
CAS:51594-55-9
MF:C3H5ClO
MW:92.52
EINECS:424-280-2
Product Categories:Industrial/Fine Chemicals;Methyl Halides;chiral;CHIRAL COMPOUNDS;Chiral Building Blocks;Glycidyl Compounds, etc. (Chiral);Oxiranes;Simple 3-Membered Ring Compounds;Synthetic Organic Chemistry;Chiral Compound;Methyl Halides;Chiral Reagents;Heterocycles;Mutagenesis Research Chemicals;Ring Systems;51594-55-9;bc0001
Mol File:51594-55-9.mol
(R)-(-)-Epichlorohydrin Structure
(R)-(-)-Epichlorohydrin Chemical Properties
Melting point -48°C
alpha 34 º (589nm, c=1, MeOH)
Boiling point 114 °C(lit.)
density 1.180 g/mL at 20 °C(lit.)
vapor density 3.29 (vs air)
vapor pressure 10 mm Hg ( 16.6 °C)
refractive index n20/D 1.438(lit.)
Fp 33 °C
storage temp. 2-8°C
solubility Chloroform (Sparingly), Methanol (Slightly)
form Liquid
color Clear colorless to very pale yellow
explosive limit21%
optical activity[α]20/D 34°, c = 1 in methanol
Water Solubility insoluble
Merck 14,3532
BRN 1420785
CAS DataBase Reference51594-55-9(CAS DataBase Reference)
NIST Chemistry ReferenceOxirane, (chloromethyl)-, (R)-(51594-55-9)
Safety Information
Hazard Codes T
Risk Statements 45-10-23/24/25-34-43
Safety Statements 53-45
RIDADR UN 2023 6.1/PG 2
WGK Germany 3
RTECS RR0427000
Autoignition Temperature772 °F
TSCA Yes
HazardClass 6.1
PackingGroup II
HS Code 29103000
MSDS Information
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(R)-(-)-Epichlorohydrin Usage And Synthesis
Chemical PropertiesColorless to light yellow liqui
Uses((R)-Epichlorohydrin) R-enantiomer of Epichlorohydrin, an important industrial chemical, is a bifunctional alkylating agent with the potential to form DNA cross-links. It is used as a solvent for natural and synthetic resins, gums, cellulose esters and ethers, paints, varnishes, nail enamels and lacquers, cement for Celluloid. Also, it is used as stabilizer.
UsesBuilding block for the synthesis of a key intermediate in the synthesis of stable PGI2 analogue UT-15.
DefinitionChEBI: (R)-epichlorohydrin is an epichlorohydrin. It is functionally related to a (S)-1,2-epoxypropane. It is an enantiomer of a (S)-epichlorohydrin.
trans-2-Chloro-3-(chloromethyl)oxirane tripchlorolide Poly(dimethylamine-co-epichlorohydrin) Hexanedioic acid, polymer with N-(2-aminoethyl)-1,2-ethanediamine, reaction products with dimethylamine and epichlorohydrin Dimer fatty acids, chloromethyloxirane, acrylic acid polymer (+)-TRANS-HEPTACHLOROEPOXIDE (+)-OXY-CHLORDANE R/S-Epichlorohydrin Fatty acids, C18-unsatd., dimers, polymers with bisphenol A, epichlorohydrin and triethylenetetramine Amides, from hydrogenated tallow and tetraethylenepentamine, polymers with epichlorohydrin and polyethylene glycol BISPHENOL A DIGLYCIDYL ETHER RESIN CIS-HEPTACHLOREPOXIDE EXO-, ISOMER B DIMETHYLAMINE/ETHYLENEDIAMINE/EPICHLOROHYDRIN COPOLYMER 2-Propenoic acid, 2-methyl-, reaction products with epichlorohydrin and formaldehyde-phenol polymer (S)-(+)-Epichlorohydrin,98+%,ALPHA-EPICHLOROHYDRIN,(S)-(+)-EPICHLOROHYDRIN 98% EPICHLOROHYDRIN, 99+% FOR ANALYTICAL PURPOSE,EPICHLOROHYDRIN, GC STANDARD,ALPHA-EPICHLOROHYDRIN,(+/-)-EPICHLOROHYDRIN, STANDARD FOR GC,Epichlorohydrin,Certified Fatty acids, C18-unsatd., dimers, polymers with bisphenol A, C18-unsatd. fatty acid trimers and epichlorohydrin (R)-(-)-Epichlorohydrin

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