(R)-(-)-3-HYDROXY-2-METHYLPROPIONIC ACID METHYL ESTER

(R)-(-)-3-HYDROXY-2-METHYLPROPIONIC ACID METHYL ESTER Basic information
Product Name:(R)-(-)-3-HYDROXY-2-METHYLPROPIONIC ACID METHYL ESTER
Synonyms:(R)-(-)-3-HYDROXYISOBUTYRIC ACID METHYL ESTER;(R)-(-)-3-HYDROXY-2-METHYLPROPIONIC ACID METHYL ESTER;(R)-(-)-METHYL B-HYDROXYISOBUTYRATE;(R)-(-)-METHYL 3-HYDROXY-2-METHYLPROPIONATE;[R]-[-]-METHYL 3-HYDROXY-2-METHYL-PROPIONATE;D(-)-BETA-HYDROXYISOBUTYRIC ACID METHYL ESTER;D-(R)-(-)-3-HYDROXYISOBUTYRIC ACID METHYL ESTER;METHYL D-(R)-3-HYDROXYISOBUTYRATE
CAS:72657-23-9
MF:C5H10O3
MW:118.13
EINECS:
Product Categories:Aliphatics;Chiral Reagents;Building Blocks for Liquid Crystals;Chiral Building Blocks;Chiral Compounds (Building Blocks for Liquid Crystals);Esters (Chiral);Functional Materials;Synthetic Organic Chemistry
Mol File:72657-23-9.mol
(R)-(-)-3-HYDROXY-2-METHYLPROPIONIC ACID METHYL ESTER Structure
(R)-(-)-3-HYDROXY-2-METHYLPROPIONIC ACID METHYL ESTER Chemical Properties
Boiling point 76-77 °C12 mm Hg(lit.)
density 1.066 g/mL at 25 °C(lit.)
refractive index n20/D 1.425
Fp 178 °F
storage temp. Sealed in dry,2-8°C
solubility Chloroform (Sparingly), Methanol (Slightly)
pka14.40±0.10(Predicted)
form Liquid
color Clear colorless
optical activity[α]19/D 26°, c = 4 in methanol
BRN 3587507
CAS DataBase Reference72657-23-9(CAS DataBase Reference)
Safety Information
Risk Statements 10
Safety Statements 16
WGK Germany 3
HS Code 29181990
MSDS Information
ProviderLanguage
SigmaAldrich English
(R)-(-)-3-HYDROXY-2-METHYLPROPIONIC ACID METHYL ESTER Usage And Synthesis
Chemical PropertiesClear Colorless Oil
UsesThe (R)- and (S)-isomers are bifunctional building blocks for the synthesis of a wide variety of optically active molecules.
UsesChiral derivative of 3-Hydroxyisobutyrate.
(R)-(-)-3-HYDROXY-2-METHYLPROPIONIC ACID METHYL ESTER Preparation Products And Raw materials
Dimethyl diethylmalonate (2S,3S)-3-Phenyl-3-hydroxy-2-methylpropionic acid methyl ester Diethyl bis(hydroxymethyl)malonate Diethyl 2-bromo-2-methylmalonate diethyl (3,4,5-trimethoxybenzoyl)malonate Yohimbine 2,2,5-Trimethyl-1,3-dioxane-4,6-dione DIETHYL DIALLYLMALONATE 3-Hydroxypropionic acid Triethyl methanetricarboxylate DIETHYL 2-ETHYL-2-(P-TOLYL)MALONATE DIETHYL DIMETHYLMALONATE 2,2-DIMETHYL-5-PHENYL-1,3-DIOXANE-4,6-DIONE EST TRIETHYL 1,1,2-ETHANETRICARBOXYLATE 5-BROMO-2.2.5-TRIMETHYL-1.3-DIOXANE-4.6-DIONE TETRAETHYL 1,1,2,2-ETHANETETRACARBOXYLATE Diethyl 1,1-cyclopropanedicarboxylate

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