ChemicalBook Product Catalog Chemical Reagents Organic reagents Aromatics ALPHA-METHYLBENZYL ALCOHOL

ALPHA-METHYLBENZYL ALCOHOL

ALPHA-METHYLBENZYL ALCOHOL Basic information
Product Name:ALPHA-METHYLBENZYL ALCOHOL
Synonyms:PHENYLMETHYLCARBINOL;PHENYLETHANOL,1-;SEC-PHENETHYL ALCOHOL;STYRENE ALCOHOL;STYRALLYL ALCOHOL;STYRALYL ALCOHOL;METHYL PHENYL CARBINEL;FEMA 2685
CAS:13323-81-4
MF:C8H10O
MW:122.16
EINECS:236-361-8
Product Categories:
Mol File:13323-81-4.mol
ALPHA-METHYLBENZYL ALCOHOL Structure
ALPHA-METHYLBENZYL ALCOHOL Chemical Properties
Melting point 19-20 °C(lit.)
Boiling point 204 °C745 mm Hg(lit.)
density 1.012 g/mL at 25 °C(lit.)
vapor density 4.21 (vs air)
vapor pressure 0.1 mm Hg ( 20 °C)
refractive index n20/D 1.527(lit.)
Fp 185 °F
CAS DataBase Reference13323-81-4(CAS DataBase Reference)
Safety Information
Hazard Codes Xn
Risk Statements 22-38-41
Safety Statements 26-39
RIDADR UN 2937 6.1/PG 3
WGK Germany 1
RTECS DO9275000
HazardClass 6.1
PackingGroup III
toxicityThe acute oral LD50 in rats was reported as 400 mg/kg (Smyth & Carpenter, 1944). The acute dermal LD50 value in rabbits exceeded 2.5 g/kg (Moreno, 1973).
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
ALPHA-METHYLBENZYL ALCOHOL Usage And Synthesis
Chemical PropertiesColorless liquid
OccurrenceHas apparently not been reported to occur in nature.
PreparationBy hydrogenation or reduction of acetophenone; or from methyl magnesium chloride plus benzaldehyde by a Grignard-type reaction (Bedoukian, 1967).
DefinitionChEBI: 1-phenylethanol is an aromatic alcohol that is ethanol substituted by a phenyl group at position 1. It has a role as a mouse metabolite.
MetabolismStyrallyl alcohol is converted in rabbits into hippuric acid and methylphenylcarbinyl glucuronide, both optical forms of the carbinol behaving similarly. A small proportion (1-2%) is excreted as mandelic acid (Wjlliams, 1959).
Purification MethodsPurify the alcohol via its hydrogen phthalate. [See Houssa & Kenyon J Chem Soc 2260 1930.] Shake it with a solution of ferrous sulfate, and th
ALPHA-METHYLBENZYL ALCOHOL Preparation Products And Raw materials
Preparation ProductsFEMA 2686-->1-Phenylethyl chloroformate-->4-METHOXY-2-(1-PHENYL-ETHYL)-PHENOL-->1-PHENYLETHAN-1,2,2,2-D4-OL-->3-(3-METHYLPHENYL)PROPIOPHENONE
ALPHA-(CHLOROMETHYL)-2,4-DICHLOROBENZYL ALCOHOL 4,4'-DICHLORO-ALPHA-METHYLBENZHYDROL 5-Phenyl-2-(2-propynylamino)-2-oxazolin-4-one alpha,alpha-dicyanobenzyl benzoate DL-Adrenalin 1-PHENYL-1,2-ETHANEDIOL Phenol Red (R)-(-)-2,2,2-TRIFLUORO-1-(9-ANTHRYL)ETHANOL DIBENZOSUBEROL 9-HYDROXYFLUORENE-9-CARBOXYLIC ACID 9-Fluorenol 1,2,3,4-TETRAHYDRO-1,5-NAPHTHALENEDIOL CYCLOPROPYL DIPHENYL CARBINOL Cumyl hydroperoxide Levisoprenaline DIBENZOSUBERENOL TETRAIODOPHENOLPHTHALEIN DECAFLUOROBENZHYDROL
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