ChemicalBook Product Catalog Chemical Reagents Desulfurizer 1-FLUOROPYRIDINIUM TRIFLATE

1-FLUOROPYRIDINIUM TRIFLATE

1-FLUOROPYRIDINIUM TRIFLATE Basic information
Product Name:1-FLUOROPYRIDINIUM TRIFLATE
Synonyms:PYRIDINIUM,1-FLUORO-TRIFLUOROMETHANESULFONIC ACID(1:1);1-FLUOROPYRIDINIUM TRIFLATE;N-FLUOROPYRIDINIUM TRIFLUOROMETHANESULFONATE;N-FLUOROPYRIDINIUM TRIFLUOROMETHANESULPHONATE;N-Fluoropyridiniumtrifluoromethanesulphonate99%;1-FLUOROPYRIDINIUM TRIFLATE, TECH;1-Fluoropyridinium Trifluoromethanesulfonate [Fluorinating Reagent];Pyridinium, 1-fluoro-, salt with trifluoromethanesulfonic acid (1:1)
CAS:107263-95-6
MF:C6H5F4NO3S
MW:247.17
EINECS:
Product Categories:Chemical Synthesis;Fluorination Reagents;Synthetic Reagents;Fluorination;Halogenation;Pyridinium Compounds;Synthetic Organic Chemistry;Electrophilic Fluorinating Reagents;Fluorinating Reagents;Fluorinating Reagents & Building Blocks for Fluorinated Biochemical Compounds
Mol File:107263-95-6.mol
1-FLUOROPYRIDINIUM TRIFLATE Structure
1-FLUOROPYRIDINIUM TRIFLATE Chemical Properties
Melting point 185-186 °C(lit.)
density 1.5493 (estimate)
storage temp. 0-6°C
form Crystalline Powder or Needles
color White to off-white
Water Solubility Reacts with water.
Sensitive Moisture Sensitive
BRN 4222821
CAS DataBase Reference107263-95-6(CAS DataBase Reference)
Safety Information
Hazard Codes C,Xi
Risk Statements 35-34
Safety Statements 26-36/37/39-45
RIDADR UN 3261 8/PG 2
WGK Germany 3
F 10-21
Hazard Note Irritant
TSCA No
HazardClass 8
PackingGroup II
HS Code 29333990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
1-FLUOROPYRIDINIUM TRIFLATE Usage And Synthesis
Chemical Propertieswhite to off-white crystalline powder or needles
UsesN-Fluoropyridinium trifluoromethanesulfonate is used as a reagent for electrophilic fluorination and for a review of electrophilic N-F fluorinating agents. It is also used as a reactant for Pd-catalyzed arylation reactions and as a fluorination agent.
UsesN-fluoropyridinium triflate salts offer a tunable fluorinating system; electronic nature of the substituents on the ring dictates the potency and selectivity of the reagent. Efficient fluorination of various aromatics, carbanions, vinyl esters, alkyls, and enamines.
UsesGeneral purpose electrophilic fluorinating reagent.4
1,1'-DI-N-OCTYL-4,4'-BIPYRIDINIUM DIBROMIDE Sulfurous Acid AMMONIUM TRIFLUOROMETHANESULFONATE 1-FLUORO-2,4,6-TRIMETHYLPYRIDINIUM TRIFLATE PYRIDINIUM TRIFLUOROMETHANESULFONATE Pyridine methanesulfonate 2,6-DICHLORO-1-FLUOROPYRIDINIUM TRIFLATE Trifluoromethanesulfonic acid 1-FLUOROPYRIDINIUM TRIFLATE 3 5-DICHLORO-1-FLUOROPYRIDINIUM TRIFLATE,3,5-DICHLORO-1-FLUOROPYRIDINIUM TRIFLATE, TECH., 85%,3 5-DICHLORO-1-FLUOROPYRIDINIUM TRIFLATE 97+%
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