4-Nitrosophenol

4-Nitrosophenol Basic information
Product Name:4-Nitrosophenol
Synonyms:P-NITROSOPHENOL;P-QUINONE MONOXIME;p-nitroso-pheno;Quinomeoxime;Quinone monoxime;Quinone(mon)oxime;quinonemonoxime;quinoneoxime
CAS:104-91-6
MF:C6H5NO2
MW:123.11
EINECS:203-251-6
Product Categories:alcohol| nitro-compound
Mol File:104-91-6.mol
4-Nitrosophenol Structure
4-Nitrosophenol Chemical Properties
Melting point 132-144°C
Boiling point 229.19°C (rough estimate)
density 1.3147 (rough estimate)
vapor pressure 0.003Pa at 20℃
refractive index 1.5423 (estimate)
solubility soluble in Methanol
pkapK1:6.48 (25°C)
form powder to crystal
color Pale-yellow, orthorhombic needles
Water Solubility <0.1 g/100 mL at 21 ºC
Merck 14,6642
Stability:Stability Flammable. Incompatible with strong oxidizing agents. Explodes when heated, or in contact with acids or alkalies.
LogP1.1 at 20℃
CAS DataBase Reference104-91-6(CAS DataBase Reference)
NIST Chemistry ReferencePhenol, 4-nitroso-(104-91-6)
EPA Substance Registry Systemp-Nitrosophenol (104-91-6)
Safety Information
Hazard Codes Xn,N
Risk Statements 21/22-40-41-68-51/53-22
Safety Statements 15-24/25-26-61-49-47-36/37/39
RIDADR 3236
RTECS SM4725000
HazardClass 4.1
PackingGroup II
HS Code 2908990000
Hazardous Substances Data104-91-6(Hazardous Substances Data)
Toxicitymmo-sat 50 mg/plate FCTXAV 18,523,80
MSDS Information
ProviderLanguage
4-Nitrosophenol English
4-Nitrosophenol Usage And Synthesis
Chemical Propertiesblack solid
UsesDyes.
HazardDangerous fire and explosion risk, reacts violently with acids and alkalies, may explode spontaneously, intraplant transport must be in tightly covered steel barrels.
Safety ProfilePoison by parented and intraperitoneal routes. Mutation data reported. An irritant and sensitizer. Many nitroso compounds are carcinogens. A very dangerous fire and explosion hazard. When exposed to heat or flame, it burns explosively. Contamination by acid or alkali may cause ignition . Can heat spontaneously and cause fire. When heated to decomposition it emits toxic fumes of NOx. See also NITROSO COMPOUNDS.
Purification Methods4-Nitrosophenol forms yellow crystals from xylene, *C6H6 (m ~144o) or Et2O (m 128-129o, dec). [Beilstein 7 H 622, 7 II 574, 7 III 3367.]
4-Nitrosophenol Preparation Products And Raw materials
Preparation ProductsSulphur Blue 7-->Sulphur Red 6-->Vat Blue 42-->Vat Blue 43-->1,4-Benzoquinone dioxime-->C.I.Leuco Sulphur Red 6-->Sulphur Red 6-->Sulphur Blue 7 -Leuco-->N-(2,4-diamino-5-(4-oxocyclohexa-2,5-dienylideneamino)phenyl)acetamide-->C.I. Sulphur Violet 5 (8CI)-->C.I. Sulphur Violet 4 (8CI)-->C.I. Sulphur Violet 3 (8CI)-->2,5-Cyclohexadien-1-one, 4-[[4-(phenylamino)phenyl]imino]-, reaction products with sodium sulfide (Na2(Sx))-->Acetamide, N-[2,4-diamino-5-[(4-oxo-2,5-cyclohexadien-1-ylidene)amino]phenyl]-, reaction products with sodium sulfide (Na2(Sx)), oxidized-->Sulfurized phenols-->C.I. Sulphur Blue 6 (8CI,9CI)-->Benzenesulfonic acid, 4-[[4-[(4-hydroxyphenyl)amino]phenyl]amino]-, reaction products with sodium sulfide (Na2(Sx)), leuco derivs.-->Leuco Sulphur Violet 3-->Leuco Sulphur Blue 2-->2,5-Cyclohexadien-1-one, 4-[[4-(phenylamino)phenyl]imino]-, reaction products with sodium sulfide (Na2(Sx)), leuco derivs.
D-BIOTIN P-NITROPHENYL ESTER 3,5-DINITROSALICYLALDEHYDE 1-NITROSO-2-NAPHTHOL-3,6-DISULFONIC ACID DISODIUM SALT 1-METHOXY-4-NITRONAPHTHALENE 1,2-(Methylenedioxy)-4-nitrobenzene 6-NITROPIPERONAL Nitrosylsulfuric acid Nitrophenol 6-NITRO-3,4-BENZOCOUMARIN 2-Methyl-4,6-dinitrophenol 3-Methyl-4-nitroanisole NITROSOGUANIDINE 4-Nitrophenol Methyl 2-nitro-3,4,5-trimethoxybenzoate EOSIN B SODIUM NITROPRUSSIDE 4-Nitrosophenol Nitroxoline

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