(1-Bromoethyl)benzene

(1-Bromoethyl)benzene Basic information
Product Name:(1-Bromoethyl)benzene
Synonyms:(±)-1-bromo-1-phenyl-ethane;(1-bromoethyl)-benzen;A-METHYLBENZYL BROMIDE;1-PHENYLETHYL BROMIDE;(1-BROMOETHYL)BENZENE;α-Methylbenzyl bromide;(1-Bromoethyl)benzene, 97% (alpha-Methybenzylbromide);(1-Bromoethyl)benzene,97%
CAS:585-71-7
MF:C8H9Br
MW:185.06
EINECS:209-560-2
Product Categories:Benzene derivates
Mol File:585-71-7.mol
(1-Bromoethyl)benzene Structure
(1-Bromoethyl)benzene Chemical Properties
Melting point -65°C
Boiling point 94 °C/16 mmHg (lit.)
density 1.356 g/mL at 25 °C (lit.)
refractive index n20/D 1.56(lit.)
Fp 179 °F
storage temp. Inert atmosphere,2-8°C
solubility Soluble in alcohol, ether, and benzene.
form Liquid
color Clear yellow to brownish
Sensitive Moisture Sensitive
BRN 507210
InChIInChI=1S/C8H9Br/c1-7(9)8-5-3-2-4-6-8/h2-7H,1H3
InChIKeyCRRUGYDDEMGVDY-UHFFFAOYSA-N
SMILESC1(C(Br)C)=CC=CC=C1
CAS DataBase Reference585-71-7(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, (1-bromoethyl)-(585-71-7)
EPA Substance Registry System(1-Bromoethyl)benzene (585-71-7)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-24/25
RIDADR UN 3334
WGK Germany 3
TSCA Yes
HS Code 29036990
Hazardous Substances Data585-71-7(Hazardous Substances Data)
MSDS Information
ProviderLanguage
alpha-Methylbenzyl bromide English
SigmaAldrich English
ACROS English
ALFA English
(1-Bromoethyl)benzene Usage And Synthesis
Chemical PropertiesCLEAR YELLOW TO BROWNISH LIQUID
Uses(1-Bromoethyl)benzene has been employed in controlled radical polymerization of styrene, in asymmetric esterification of benzoic acid in the presence of a chiral cyclic guanidine and as initiator in the synthesis of bromine terminated polyp-methoxystyrene and polystyrene via atom transfer radical polymerization.
Synthesis Reference(s)The Journal of Organic Chemistry, 48, p. 1678, 1983 DOI: 10.1021/jo00158a018
Synthesis, p. 383, 1981
(1-Bromoethyl)benzene Preparation Products And Raw materials
Preparation Products1-(1-PHENYLETHYL)PIPERAZINE-->Benzenemethanol, ar-methyl-, acetate
1-bromo-2-(2-bromoethyl)benzene Phenethyl chloride Rocuronium bromide (1,2-DIBROMOETHYL)BENZENE Decabromodiphenyl Ethane 4-Ethylacetophenone 3-BROMO-1-(2-BROMOETHYL)BENZENE Benzbromarone Ethylbenzene Sodium bromate 3-FLUOROPHENETHYL BROMIDE Benzene Ethidium bromide Allyl bromide Benzyldodecyldimethylammonium bromide (1-Bromoethyl)benzene Methyl bromide Diethylstilbestrol

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