1-PHENYLSEMICARBAZIDE

1-PHENYLSEMICARBAZIDE Basic information
Product Name:1-PHENYLSEMICARBAZIDE
Synonyms:2-phenylhydrazide,carbamicacid;2-phenyl-hydrazinecarboxamid;2-phenylhydrazinecarboxamide;Carbamic acid, 2-phenylhydrazide;carbamicacid,2-phenylhydrazide;Carbaphen;Cryogenine (pharmaceutical);1-Phenylsemicarbazide,99%
CAS:103-03-7
MF:C7H9N3O
MW:151.17
EINECS:203-072-3
Product Categories:Carbonyl Compounds;Organic Building Blocks;Ureas
Mol File:103-03-7.mol
1-PHENYLSEMICARBAZIDE Structure
1-PHENYLSEMICARBAZIDE Chemical Properties
Melting point 171-174 °C (lit.)
Boiling point 273.17°C (rough estimate)
density 1.2100 (rough estimate)
refractive index 1.5860 (estimate)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility acetone: very soluble(lit.)
pka11.16±0.43(Predicted)
form powder to crystal
color White to Light yellow
BRN 743311
CAS DataBase Reference103-03-7(CAS DataBase Reference)
IARC3 (Vol. 12, Sup 7) 1987
EPA Substance Registry SystemPhenicarbazide (103-03-7)
Safety Information
Hazard Codes Xn
Risk Statements 22
Safety Statements 45-36/37/39-26
WGK Germany 3
RTECS FD0575000
TSCA Yes
HS Code 29280090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
1-PHENYLSEMICARBAZIDE Usage And Synthesis
Uses1-Phenylsemicarbazide was used in the synthesis of a series of alkyl(aryl/heteroaryl) substituted 3-trifluoromethyl-1H-1-phenylpyrazoles and alkyl 3-carboxylate analogs by the cyclocondensation reactions with 4-alkoxy-1,1,1-trihaloalk-3-en-2-ones.
DefinitionChEBI: Phenicarbazide is a member of phenylhydrazines.
Brand nameAntipyretic dellepsoids d26.
World Health Organization (WHO)Phenicarbazide, which has analgesic and antipyretic activity, was introduced in the 1970s. It has been withdrawn in at least one country on grounds of its adverse effect profile and it appears to have fallen into disuse in others.
Purification MethodsCrystallise it from water and dry it in a vacuum over KOH. [Beilstein 15 H 287, 15 II 106, 15 III 184, 15 IV 180.]
1,5-BIS(4-NITROPHENYL)CARBOHYDRAZIDE 1-(2,3,5,6-TETRAFLUORO-4-METHYLPHENYL)-4-(3,4-DICHLOROPHENYL)SEMICARBAZIDE N1-(2,6-DICHLORO-4-PYRIDYL)-2-(2,4,6-TRICHLOROPHENYL)HYDRAZINE-1-CARBOXAMIDE 1-PHENYLURAZOLE 1-(4-Methylphenyl)semicarbazide N1-(2,6-DICHLORO-4-PYRIDYL)-2-[2-(TRIFLUOROMETHYL)PHENYL]HYDRAZINE-1-CARBOXAMIDE 1,4-DIPHENYLSEMICARBAZIDE DIPHENYLCARBAZONE-BROMOPHENOL BLUE 4-(2-CHLOROPHENYL)SEMICARBAZIDE N1-(2,6-DICHLORO-4-PYRIDYL)-2-(2,4-DIFLUOROPHENYL)HYDRAZINE-1-CARBOXAMIDE N1-(2,6-DICHLORO-4-PYRIDYL)-2-(3,5-DICHLOROPHENYL)HYDRAZINE-1-CARBOXAMIDE 5-METHYL-1-PHENYL-1,2,4-TRIAZOLIN-3-ONE N1-(2,6-DICHLORO-4-PYRIDYL)-2-(4-NITROPHENYL)HYDRAZINE-1-CARBOXAMIDE 1-(4-FLUOROPHENYL)SEMICARBAZIDE 1-(2,3,5,6-TETRAFLUORO-4-METHYLPHENYL)-4-(3-(TRIFLUOROMETHYL)PHENYL)SEMICARBAZIDE N-([2-(2,4-DICHLOROPHENYL)HYDRAZINO]CARBONYL)-2-METHYL-4-(TRIFLUOROMETHYL)-1,3-THIAZOLE-5-CARBOXAMIDE 1-(2-(INDOL-3-YL)-ACETYL)-4-PHENYLSEMICARBAZIDE 1-(4-(2-NITRO-4-(TRIFLUOROMETHYL)PHENOXY)BENZOYL)-1-PHENYLSEMICARBAZIDE

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