| | N,N-Diethylaniline Basic information |
| Product Name: | N,N-Diethylaniline | | Synonyms: | N,N-DIETHYLANILINE, 98%N,N-DIETHYLANILINE, 98%N,N-DIETHYLANILINE, 98%;N,N-DiethylbenzeneaMine;Phenyldiethylamine;Pregna-1,4-diene-3,20-dione, 17,21-bis(acetyloxy)-2-bromo-6,9-difluoro-11-hydroxy-, (6b,11b)-;coMpound with borane;N,N-Diethylaniline, 99% 250ML;N,N-Diethylaniline, 99% 5ML;N,N-Diethylaniline puriss. p.a., >=99.5% | | CAS: | 91-66-7 | | MF: | C10H15N | | MW: | 149.23 | | EINECS: | 202-088-8 | | Product Categories: | Amines;Building Blocks;C10;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks;Intermediates of Dyes and Pigments;Organics;organic chemical;bc0001 | | Mol File: | 91-66-7.mol |  |
| | N,N-Diethylaniline Chemical Properties |
| Melting point | -38 °C | | Boiling point | 217 °C(lit.) | | density | 0.938 g/mL at 25 °C(lit.) | | vapor density | 5.2 (vs air) | | vapor pressure | 1 mm Hg ( 49.7 °C) | | refractive index | n20/D 1.542(lit.) | | Fp | 208 °F | | storage temp. | Store below +30°C. | | solubility | water: soluble1g in 70ml at 12°C | | pka | 6.61(at 22℃) | | form | Liquid | | color | Clear yellow | | PH | 8 (0.1g/l, H2O, 20℃) | | explosive limit | 1.1-5.3%(V) | | Water Solubility | 14 g/L (12 ºC) | | Merck | 14,3114 | | BRN | 742483 | | Stability: | Stable. Combustible. Incompatible with strong oxidizing agents, strong acids. | | LogP | 3.904 at 25℃ | | CAS DataBase Reference | 91-66-7(CAS DataBase Reference) | | NIST Chemistry Reference | Benzenamine, N,N-diethyl-(91-66-7) | | EPA Substance Registry System | N,N-Diethylaniline (91-66-7) |
| Hazard Codes | T,N | | Risk Statements | 23/24/25-33-51/53 | | Safety Statements | 28-37-45-61-28A | | RIDADR | UN 2432 6.1/PG 3 | | WGK Germany | 2 | | RTECS | BX3400000 | | F | 8 | | Autoignition Temperature | 500 °C | | Hazard Note | Toxic | | TSCA | Yes | | HS Code | 2921 42 00 | | HazardClass | 6.1 | | PackingGroup | III | | Hazardous Substances Data | 91-66-7(Hazardous Substances Data) | | Toxicity | LD50 orally in Rabbit: 610 mg/kg LD50 dermal Rat > 5000 mg/kg |
| | N,N-Diethylaniline Usage And Synthesis |
| Chemical Properties | light yellow liquid | | Chemical Properties | N,N-Diethylaniline is a pale yellow liquid. It is
slightly soluble in water (1.40 g/L at 12°C), and soluble in
alcohol and ether. | | Uses | N,N-Diethylaniline is used in dyestuffs and in the synthesis of
other intermediates and pharmaceuticals. | | Uses | As dyestuff intermediate, in organic syntheses. | | Uses | DEA (diethanolamine) is an organic alkali used in formulations to neutralize organic acids and thus adjust pH. It is usually listed on ingredient labels preceding the compound that it is neutralizing. oleth-3 phosphate, for example, is a powerful emulsifier, but it is very acidic when it is made, so manufacturers use DeA to neutralize it and improve the nature of a formulation. | | Synthesis Reference(s) | Chemistry Letters, 15, p. 293, 1986
Journal of the American Chemical Society, 95, p. 3038, 1973 DOI: 10.1021/ja00790a064 | | General Description | A colorless to yellow liquid with a fishlike odor, that is strongly corrosive. Irritating to skin, eyes and mucous membranes and moderately toxic by inhalation, absorption and ingestion. Flash point 185°F. Used in dyes and in the production of organic chemicals. | | Air & Water Reactions | Insoluble in water. | | Reactivity Profile | N,N-Diethylaniline neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. | | Health Hazard | May be fatal if inhaled, swallowed or absorbed through the skin. Vapor or mist is irritant to the eyes, mucous membranes, upper respiratory tract; causes skin irritation. Absorption into the body leads to the formation of methemoglobin which, in sufficient concentration, may cause cyanosis. Onset may be delayed 2-4 hours or longer. Exposure can cause nausea, dizziness, headache, damage to the eyes, and blood effects. | | Fire Hazard | Special Hazards of Combustion Products: Emits toxic fumes under fire conditions. | | Flammability and Explosibility | Nonflammable | | Safety Profile | Moderately toxic by
ingestion and intraperitoneal routes. When
heated to decomposition it emits toxic
fumes of NOx. See also ANILINE DYES. | | Purification Methods | Reflux the base for 4hours with half its weight of acetic anhydride, then fractionally distil it under reduced pressure (b 92o/10mm). [Beilstein 12 IV 252.] |
| | N,N-Diethylaniline Preparation Products And Raw materials |
| Raw materials | Ethanol-->Aniline | | Preparation Products | XANTHOTOXOL-->4,6-DIAMINO-5-NITROPYRIMIDINE-->4,5-DIAMINO-6-METHYLPYRIMIDINE-->N-(2-Amino-4,6-dichloro-5-pyrimidinyl)formamide-->5-BROMO-2-CHLORO-4-(DIMETHYLAMINO)PYRIMIDINE-->TRIOXSALEN-->2,4-Dichloro-5-cyanopyrimidine-->2,4-dichloropyrimidine-5-carbonitrile-->6-AMINO-5-NITROPYRIMIDIN-4-OL-->2-Bromofuran-->2,4,6-TRICHLOROPYRIMIDIN-5-AMINE-->2-CHLORO-5-NITROPYRIMIDIN-4-AMINE-->4,6-DICHLORO-1H-PYRAZOLO[3,4-D]PYRIMIDINE-->8-HYDROXY-7-METHOXYCOUMARIN-->2,4,6-TRICHLORO-5-NITROPYRIMIDINE-->2,4-Dichloro-6-methyl-5-nitropyrimidine-->4-AMINO-2-CHLORO-6-METHYL-5-NITROPYRIMIDINE-->2-METHOXY-5-NITROPYRIMIDIN-4-AMINE-->2-CHLORO(BROMO)PYRIMIDINE-->2-CHLORO-4,5-DIAMINOPYRIMIDINE-->2,4-Dichloro-5-nitropyrimidine-->Scopoletin-->N,N-Diethyl-p-phenylenediamine sulfate-->N,N-DIETHYL-P-PHENYLENEDIAMINE MONOHYDROCHLORIDE-->4,4'-Benzylidenebis[N,N-diethylaniline |
|
