4-Methyl-3-nitropyridine

4-Methyl-3-nitropyridine Basic information

Product Name:	4-Methyl-3-nitropyridine
Synonyms:	4-METHYL-3-NITROPYRIDINE;pyridine, 4-Methyl-3-nitro-;3-Nitro-4-methylpyridine;3-nitro-4-picoline;Pyridine, 4-methyl-3-nitro- (9CI);Methyl-3-nitropyridine,4-;4-Methyl-3-nitropyridine,98%;4-Methyl-3-nitropyridine 97%
CAS:	5832-44-0
MF:	C6H6N2O2
MW:	138.12
EINECS:	628-685-7
Product Categories:	Heterocycle-Pyridine series;NITRO;Pyridine series;Pyridine;C6;Heterocyclic Building Blocks;Pyridines
Mol File:	5832-44-0.mol

4-Methyl-3-nitropyridine Chemical Properties

Melting point	24-28 °C
Boiling point	238 °C
density	1.228 g/mL at 25 °C
refractive index	n20/D 1.549
Fp	227 °F
storage temp.	Inert atmosphere,Room Temperature
pka	1.87±0.18(Predicted)
form	powder to lump to clear liquid
color	White or Colorless to Yellow
BRN	118796
CAS DataBase Reference	5832-44-0(CAS DataBase Reference)

Safety Information

Hazard Codes	Xn,T,Xi
Risk Statements	22-37/38-41-36/37/38
Safety Statements	26-39-36
RIDADR	2810
WGK Germany	3
Hazard Note	Harmful
HazardClass	6.1
PackingGroup	III
HS Code	29333990

MSDS Information

Provider	Language
4-Methyl-3-nitropyridine	English
SigmaAldrich	English
ALFA	English

4-Methyl-3-nitropyridine Usage And Synthesis

Chemical Properties	Deliquescent cryst
Uses	4-Methyl-3-nitropyridine may be used as a starting material in the synthesis of ethyl 6-azaindole-2-carboxylate and also 3-substituted azaindoles.
Uses	4-METHYL-3-NITROPYRIDINE is a useful research chemical.
General Description	4-Methyl-3-nitropyridine, a substituted nitropyridine, can be prepared by the malonation of 4-methoxy-3-nitropyridine with sodium diethyl malonate.

4-Methyl-3-nitropyridine Preparation Products And Raw materials

Raw materials	Sodium hydroxide-->Ethyl acetate-->Dichloromethane-->PETROLEUM ETHER-->Nitric acid-->Sodium sulfate-->Trifluoroacetic acid-->Trifluoroacetic anhydride-->Sodium metabisulfite-->Potassium nitrate-->4-Methylpyridine
Preparation Products	3-NITROISONICOTINALDEHYDE-->ethyl 3-(3-nitropyridin-4-yl)-2-oxopropanoate-->N,N-Dimethyl-N-[(E)-2-(3-nitropyridin-4-yl)vinyl]amine

nitrotoluene 4,6-Dimethyl-2-hydroxy-5-nitronicotinonitrile Bensulfuron methyl 2-CHLORO-4,6-DIMETHYL-5-NITRO-NICOTINONITRILE 2-Chloro-5-chloromethylpyridine 2-HYDROXY-5-NITRO-4-PICOLINE (2-HYDROXY-4-METHYL-5-NITROPYRIDINE) Parathion-methyl 4-Methylpyridine Azamethiphos ETHYL 2-CHLORO-3-CYANO-6-METHYL-5-NITROPYRIDINE-4-CARBOXYLATE 2-AMINO-3-NITRO-4-PICOLINE (2-AMINO-4-METHYL-3-NITROPYRIDINE) 2,6-Lutidine 2,4,6-Collidine 6-CHLORO-5-CYANO-4-METHOXYMETHYL-3-NITRO-2-PICOLINE 3-chloro-4-methyl-5-nitropyridine,2-CHLORO-5-NITRO-4-PICOLINE (2-CHLORO-4-METHYL-5-NITROPYRIDINE) 4-Methyl-3-nitropyridine Methyl acetate METHYL THIOPHENE-2-CARBOXYLATE

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