(2S)-(+)-Glycidyl tosylate

(2S)-(+)-Glycidyl tosylate Basic information
Product Name:(2S)-(+)-Glycidyl tosylate
Synonyms:(S)-Glycidyl Tosylate,99%e.e.;2-Oxiranylmethyl 4-methylbenzenesulfonate;4-methylbenzenesulfonate,(s)-oxiranemethano;(S)-Oxiran-2-ylMethyl 4-Methylbenzenesulfonate;(2S)-2-OxiraneMethanol 2-(4-Methylbenzenesulfonate);(S)-(2,3-Epoxypropan-1-yl) 4-Methylbenzenesulfonate;(S)-Oxiran-2-ylMethyl Toluene-4-sulfonate;(S)-Toluene-4-sulfonic Scid OxiranylMethyl Ester
CAS:70987-78-9
MF:C10H12O4S
MW:228.26
EINECS:417-210-7
Product Categories:Carbohydrates & Derivatives;Sulfur & Selenium Compounds;Phenyls & Phenyl-Het;chiral;CHIRAL COMPOUNDS;Aromatics;Chiral Compound;Phenyls & Phenyl-Het
Mol File:70987-78-9.mol
(2S)-(+)-Glycidyl tosylate Structure
(2S)-(+)-Glycidyl tosylate Chemical Properties
Melting point 46-49 °C(lit.)
alpha 17 º (c=2.5, CHCl3)
Boiling point 340.07°C (rough estimate)
density 1.3749 (rough estimate)
refractive index 1.5400 (estimate)
Fp >230 °F
storage temp. 2-8°C
solubility Dioxane (Slightly), DMSO (Slightly), Methanol (Slightly)
form Fluffy Powder
color White
Water Solubility decomposes
BRN 3592143
CAS DataBase Reference70987-78-9(CAS DataBase Reference)
NIST Chemistry Reference(2S)-glycidyl tosylate(70987-78-9)
Safety Information
Hazard Codes T,N,Xi
Risk Statements 45-41-43-51/53-68
Safety Statements 53-45-61
RIDADR UN 3077 9/PG 3
WGK Germany 3
RTECS RR0510050
3-10-21
HazardClass 9
PackingGroup III
HS Code 29109000
MSDS Information
ProviderLanguage
(2S)-(+)-Glycidyl tosylate English
SigmaAldrich English
ACROS English
(2S)-(+)-Glycidyl tosylate Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
UsesUsed in the first enantioselective synthesis of (R)- and (S)-4-acetyl-3-(hydroxymethyl)-3,4-dihydro-2H-pyrido[3,2-b]oxazines.
Uses(2S)-(+)-Glycidyl tosylate is protected Glycidol, used as an intermediate in the preparation of neurochemicals.
(2S)-(+)-Glycidyl tosylate Preparation Products And Raw materials
Preparation Products(S)-2-Oxiranylanisole-->(S)-2-((3-CHLOROPHENOXY)METHYL)OXIRANE
4-CHLOROBENZOYLACETONITRILE Sodium p-toluenesulfonate 1,6:3,4-DIANHYDRO-2-O-TOSYL-BETA-D-GALACTOPYRANOSE R(-)or S(+) glycidyl tosylate p-Toluenesulfonic acid PROPYL P-TOLUENESULFONATE (S)-Oxiranemethanol ETHYLENE OXIDE GLYCIDYL ACRYLATE Sodium xylenesulfonate (R)-(+)-Glycidol (S)-(+)-2-HYDROXYPROPYL P-TOLUENESULFONATE Methanol GLYCIDYL 4-TOLUENESULFONATE (2S)-(+)-Glycidyl tosylate Sorafenib tosylate 1,2-EPOXYTETRADECANE (2R)-(-)-Glycidyl tosylate

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