Methyl 3-methyl-2-butenoate

Methyl 3-methyl-2-butenoate Basic information
Product Name:Methyl 3-methyl-2-butenoate
Synonyms:2-Butenoicacid,3-methyl-,methylester;3-Methyl-2-butenoic acid, methyl ester;3-methyl-2-butenoicacimethylester;3-Methylcrotonic acid methyl ester;Crotonic acid, 3-methyl-, methyl ester;dimethylacrylicacidmethylester;Methyl 3,3-dimethacrylate;methyl 3-methylbut-2-enoate
CAS:924-50-5
MF:C6H10O2
MW:114.14
EINECS:213-107-4
Product Categories:fine chemicals;ester series;(intermediate of Gancyclovir);bc0001
Mol File:924-50-5.mol
Methyl 3-methyl-2-butenoate Structure
Methyl 3-methyl-2-butenoate Chemical Properties
Melting point -41°C
Boiling point 70-75 °C60 mm Hg(lit.)
density 0.935 g/mL at 20 °C
refractive index n20/D 1.4364(lit.)
Fp 99 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form clear liquid
color Colorless to Almost colorless
Water Solubility Soluble in chloroform. Insoluble in water,
λmax216nm(CH3CN)(lit.)
Sensitive Light Sensitive
BRN 1741592
LogP1.715 (est)
CAS DataBase Reference924-50-5(CAS DataBase Reference)
NIST Chemistry Reference2-Butenoic acid, 3-methyl-, methyl ester(924-50-5)
EPA Substance Registry System2-Butenoic acid, 3-methyl-, methyl ester (924-50-5)
Safety Information
Hazard Codes Xi
Risk Statements 10
Safety Statements 16-29-33
RIDADR UN 3272 3/PG 3
WGK Germany 1
8
Hazard Note Irritant
TSCA Yes
HazardClass 3
PackingGroup III
HS Code 29161900
MSDS Information
ProviderLanguage
Methyl 3,3-dimethylacrylate English
SigmaAldrich English
ALFA English
Methyl 3-methyl-2-butenoate Usage And Synthesis
Chemical PropertiesColorless liquid
UsesMethyl 3,3-dimethylacrylate is an important raw material and intermediate used in organic synthesis, pharmaceuticals agrochemicals and dyestuff fields.
Synthesis Reference(s)Journal of the American Chemical Society, 71, p. 3214, 1949 DOI: 10.1021/ja01177a079
General DescriptionMethyl 3-methyl-2-butenoate is an α,β-unsaturated ester. It is reported as overripe fruity, ethereal odorant, responsible for the aroma of snake fruit. Rate coefficients for the reaction between the NO3 radical and methyl 3-methyl-2-butenoate has been evaluated.
Methylparaben Paraquat dichloride tiglic acid Acetonitrile 4-METHYLESCULETIN 7-Acetoxy-4-methylcoumarin AFLATOXIN G1 Basic Violet 1 POLY(METHYL METHACRYLATE) 5-Carbethoxy-4,6-dimethyl-2-pyrone 3-[2-(DIETHYLAMINO)ETHYL]-7-HYDROXY-4-METHYLCOUMARIN HYDROCHLORIDE Kresoxim-methyl Methyl 2,2-dimethylphenylacetate Methanol Methyl 3-methyl-2-butenoate Methyl acrylate Methyl methacrylate Methyl bromide

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