Carbonylchlorohydrotris(triphenylphosphine)ruthenium

Carbonylchlorohydrotris(triphenylphosphine)ruthenium Basic information
Reaction
Product Name:Carbonylchlorohydrotris(triphenylphosphine)ruthenium
Synonyms:CARBONYLCHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II);carbonylchlorohydridotris(triphenyl-phosphine)rut;carbonylchlorohydrotris(triphenylphosphine)ruthenium;Hydridochlorocarbonyltris-(triphenylphosphino)-ruthenium;Carbonylchlorohydridotris(triphenylphosphine)ruthenium;Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II),99%;Ru(CO)ClH(PPh3)3;RuHCl(CO)(PPh3)3
CAS:16971-33-8
MF:C55H45ClOP3Ru
MW:951.39
EINECS:241-051-0
Product Categories:Ru;metal carbonyl complex;Catalysis and Inorganic Chemistry;Ru Catalysts;Ruthenium
Mol File:16971-33-8.mol
Carbonylchlorohydrotris(triphenylphosphine)ruthenium Structure
Carbonylchlorohydrotris(triphenylphosphine)ruthenium Chemical Properties
Melting point 204-206 °C (dec.)(lit.)
Boiling point approximate 360℃
storage temp. Keep in dark place,Inert atmosphere,Room temperature
form Powder
color Cream to tan
Water Solubility insoluble
Sensitive Air stable, light sensitive
Safety Information
Hazard Codes Xn,T
Risk Statements 20/21/22-36/37/38
Safety Statements 26-37/39-36/37/39-22
WGK Germany 3
HS Code 29310099
MSDS Information
ProviderLanguage
SigmaAldrich English
Carbonylchlorohydrotris(triphenylphosphine)ruthenium Usage And Synthesis
Reaction
  1. Catalyst for alcohol α-allylation with dienes or allenes under transfer hydrogenation conditions.
  2. Catalyst for tandem isomerization (to imine), followed by Friedel Crafts alkylation.
  3. Catalyst for amination of alcohols with ammonia.
Reactions of 16971-33-8
Chemical Propertiespale yellow crystals
UsesCarbonylchlorohydridotris(triphenylphosphine)ruthenium(II) is used as a raw material to synthesize other ru-hydride catalysts. It is involved in the hydrogenation of ring-opening metathesis polymers such as norbornene and other cyclic olefin ROMP polymers used as plastics, resins and optical materials. It can act as an alternative catalyst to rhodium hydrogenation catalyst. It also serves as a catalyst in the hydrogenation of conjugated diene copolymers like acrylonitrile-butadiene rubber (NBR).
Carbonylchlorohydrotris(triphenylphosphine)ruthenium Preparation Products And Raw materials
Palladium (II) Acetate Platinum dioxide Tris(dibenzylideneacetone)dipalladium Tris(triphenylphosphine)rhodiu Chloroplantinic acid [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Iridium(III) acetylacetonate Tris(triphenylphosphine)ruthenium(II) chloride DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) Hexachloroiridic acid hexahydrate Carbonyldihydrotris(triphenylphosphine)ruthenium Tris(dibenzylideneacetone)dipalladium METHOXYCARBONYLSULFENYL CHLORIDE Ruthenium(III) chloride Ruthenium CHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) Carbonylchlorohydrotris(triphenylphosphine)ruthenium Triphenylphosphine

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